没食子酸在含盐酸高温液态水中的稳定性.docVIP

  没食子酸在含盐酸高温液态水中的稳定性# 5 10 15 20 25 30 35  摘要：为开发含盐酸高温液态水中单宁水解制备没食子酸的绿色工艺，采用间隙高压反应釜 研究了没食子酸在含盐酸高温液态水中的稳定性。在数据重现性研究基础上，考察了没食子 酸初始浓度、盐酸浓度和反应温度对没食子酸稳定性的影响，结果表明：盐酸浓度对没食子 酸的稳定性有较显著的影响，随着盐酸浓度的增加稳定性下降；温度对没食子酸稳定性影响 十分显著，随着温度的升高，没食子酸转化速率快速增加，稳定性显著降低，但 413.15K 以 下没食子酸在盐酸溶液中有较好的稳定性。采用拟一级反应动力学方程，拟合得到了不同盐 酸浓度和反应温度下的反应速率常数，进而利用 Arrhenius 方程得到了不同盐酸浓度下没食 子酸脱羧反应的表观活化能，拟合结果表明盐酸存在下没食子酸脱羧反应的表观活化能均在 112 kJ/mol 附近，且随着盐酸浓度的增加变化不大。 关键词：没食子酸；稳定性；高温液态水；盐酸；动力学 中图分类号：O625.52, O625.31+2 Stability of Gallic Acid in High Temperature Liquid Water with Hydrochloric Acid ZHANG Yingjie1, FU Jie1, LIU Lin2, LU Xiuyang1 (1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, HangZhou 310027; 2. Zunyi Shanlin Botanical Chemicals Co., Ltd, GuiZhou ZunYi 563000) Abstract: To develop a green technology for the HCl-catalyzed hydrolysis of tannin in high temperature liquid water to produce gallic acid, the stability of gallic acid in high temperature liquid water with hydrochloric acid was studied in a high-pressure batch reactor. After the study on the data repeatability, the effects of initial concentration of gallic acid, concentration of hydrochloric acid and reaction temperature on the stability of gallic acid were investigated. The results indicate that HCl concentration has a significant effect on the stability of gallic acid. The stability of gallic acid decreases as the concentration of HCl increases. Reaction temperature remarkably influences the stability of gallic acid. As the temperature increases, the conversion rate of gallic acid increases rapidly, and the stability of gallic acid decreases remarkably. Below 413.15K, gallic acid was relatively stable in HCl solution. The kinetics data of gallic acid stability were fitted by a pesudo-first-order kinetics equation to obtain the rate constants at different hydrochloric acid concentrations and reaction temperatures. The apparent activation energies fo