铺展条件对PS_PS-b-PMMA共混物Langmuir单层及其LB膜的影响.docVIP

  铺展条件对 PS/PS-b-PMMA 共混物 Langmuir 单层及其 LB 膜的影响# 5 10 15 20 25 30  摘要：本文主要利用 Langmuir 膜天平和原子力显微镜 (AFM)对聚苯乙烯（PS）与苯乙烯- 甲基丙烯酸甲酯嵌段共聚物（PS-b-PMMA）共混物在空气/水界面的聚集行为及其 LB 膜的 表面形态结构进行了研究。具体考察了选择性溶剂对不同组成的 PS/PS-b-PMMA 共混物的 Langmuir 单层及其 LB 膜的影响。结果表明，随着 PS 含量的增加π-A 等温线逐渐向左移动。 PS 含量的变化，影响了 PS-b-PMMA 在水面上的铺展。随着 PS 含量的增大，胶束由圆形胶 束和几何形状不规则的平面胶束结构转变成圆形与尺寸均一的平面胶束结构，最后转变成项 链-网络结构。 关键词：高分子共混物；LB 膜；AFM 中图分类号：O631.1 Effect of Spreading Condition on the Mixed Langmuir Monolayers and LB Films of PS and PS-b-PMMA FANG Liming1, WEN Gangyao1, ZHAO Fengyang1, SHI Tongfei2, AN Lijia2 (1. Department of Polymer Materials and Engineering, College of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040; 2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, ChangChun 130022) Abstract: The Langmuir film balance technology and atomic force microscopy (AFM) were used to study the aggregation behavior of the mixed Langmuir monolayer of PS and polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA, SMMA). The effect of selective solvent on the different contents mixed Langmuir monolayers and LB films of PS/PMMA is specifically studied. With the increase of PS content, the π-A isotherms shift to the left. The diversification of the PS content effects the spreation of the PS-b-PMMA on the water. With the increase of the PS content exhibit from the mixed structure of circular micelles and irregular geometry plane micelles to circular and plane micelles with uniform size and finally turn to necklace- network structure. Key words: Polymer blend; LB film; AFM 35 0 引言 近年来，Langmuir-Blodgett（LB）膜技术已经受到国际科技界的广泛关注。目前人们对 二元高分子共混体系进行了相关的研究，其中具有代表性的是苯乙烯-b-二戊铁基硅烷/苯乙 烯-2-乙烯吡啶嵌段共聚物（PS-b-FS/ PS-b-P2VP）[1]、聚甲基丙烯酸甲酯/异戊二烯-甲基丙 40 烯酸甲酯嵌段共聚物（PMMA/PI-b-PMMA）[2]、聚苯乙烯/聚己内酯（PS/PCL）[3]、聚苯乙 烯/聚乙烯基甲基醚（PS/PVME）[4]，PS/PS-b-P2VP [5,6]，PS/PS-b-PMMA[7]等共混体系，其 中文纲要[5,6]等人认为 Homo-PS 的含量达到 80%-95%时，通过 AFM 首次观察到非常均一， -1-   稳定