Bi2WO6花瓣状微球的无助剂合成及其光催化性能.docVIP

  Bi2WO6 花瓣状微球的无助剂合成及其光催 化性能# * 5 10 15 20 25 30 35  摘要：以 Bi(NO3)3· 5H2O 和 Na2WO4· 2H2O 为原料，采用水热法无助剂合成了 Bi2WO6 花瓣状微球，以罗丹明 B（RhB）为降解模型，考察了水热温度、水热时间和前驱体溶液的 pH 对 Bi2WO6 微球光催化性能的影响，其中前驱体溶液的 pH 对 Bi2WO6 微球性能影响最 大。前驱体溶液为酸性时利于花瓣状 Bi2WO6 微球的生成，前驱体溶液为碱性时发现有 Bi3.84W0.16O6.24 生成。利用 SEM、XRD、BET、UV-vis DRS 等方法对 Bi2WO6 微球进行 了形貌与结构表征。结果表明：在理想条件下合成出的产物为斜方晶型的 Bi2WO6 花瓣状 微球，直径在 500nm~3μm 之间，比表面积为 27.9m2/g，氙灯光照 75min，对 20mg/L 的 RhB 降解率（η）可以达到 100%，说明花瓣状 Bi2WO6 微球具有优良的可见光催化活性。 关键词：无助剂水热法，花瓣状 Bi2WO6 微球，RhB，可见光催化 中图分类号：O 643.32 No-additive synthesis of petal-like Bi2WO6 microspheres and photocatalytic activity WANG Lianjun, YAO Binghua, PENG Chao (Department of Applied Chemistry,Xian University of Technology,Xian 710048) Abstract: Bi(NO3)3· 5H2O and Na2WO4· 2H2O were used as raw materials, the petal-like Bi2WO6 microspheres were synthesized by no-additive hydrothermal method. Using Rhodamine B （RhB）as a model compound, the effects of the hydrothermal pH value, temperature and time on the photocatalytic activity of the Bi2WO6 was tested。The precursor’s pH value is a main factor for the photocatalytic activity of Bi2WO6, the acidic condition was good for the formation of petal-like Bi2WO6 microspheres. It was found that the Bi3.84W0.16O6.24 generated when the precursor solution was alkaline. The as-prepared samples were characterized by X-ray diffraction(XRD), scanning electron microscope (SEM), Brunauer-Emmett-Teller（BET）and UV-vis DRS. The results showed that the product was petal-like Bi2WO6 microspheres with orthorhomibc structure, it had an average diameter of 500nm-3μm and a high specific surface area (27.91m2/g)，The degradation rate(η) of RhB(20mg/L) reached to 100% after 75 minutes lighting with xenon lamp. This showed that the petal-like Bi2WO6 microspheres synthesized by hydrothermal method had an excellent visible light photocatalytic activity. Key words: no-additive hydrothermal method; prtal-like Bi2WO6 microspheres; Rhodamine B; visible light photocatalysis 0 引言 近年来，越来越多