SPE电解阳极催化剂用介孔V掺杂TiO2载体研究.docVIP

  SPE 电解阳极催化剂用介孔 V 掺杂 TiO2 载 体研究# 吕洪，马建新，郝传璞* 5 10 15 20 25 30 35 40 （同济大学汽车学院，上海 201804） 摘要：本文采用溶剂蒸发自组装法（EISA）来制备掺杂介孔 TiO2，通过调整钛水比、蒸发 条件、焙烧温度等方面制备出不同比表面积和孔径分布的掺杂 TiO2。分别对比表面积相当、 不同掺杂量的 IrO2/Ti(1-x)VxO2（x = 0、0.01、0.05）载体利用亚当斯熔融法（Adams Fusion Method）负载 IrO2 纳米颗粒。XRD 与 TEM 实验结果显示，Ti(1-x)VxO2 载体在负载 IrO2 后发生了锐钛矿到金红石的相转变，新相晶粒有所长大，但随着 V 掺杂量的增多晶粒生长 受到抑制；BET 结果表明在负载 IrO2 后整体比表面积有所降低，未掺 V 的样品降低程度较 大；在 0.1M HClO4 溶液及 N2 气氛下对 40 wt%担载量的 IrO2/Ti(1-x)VxO2（x = 0、0.01、 0.05）和纯 IrO2 进行了循环伏安测试，电流密度随着 V 掺杂量的提高而显著提高，证明 V 掺杂手段可以显著提高复合催化剂的导电性以及催化活性，有望通过进一步改进使 V 掺杂 TiO2 成为新型的 SPE 阳极载体材料。 关键词：SPE 电解；析氧反应；介孔 TiO2；载体；IrO2 中图分类号：TQ116.2 INVESTIGATION OF MESOPOROUS VANADIUM DOPED TIO2 SUPPORT FOR ANODE CATALYST OF SPE ELECTROLYZER Lv Hong1, Ma Jianxin1, Hao Chuanpu2 (1. School of Automotive Studies, Tongji University, Shanghai, 201804; 2. School of Automotive Studies, Tongji University, Shanghai 201804) Abstract: This paper focused on the preparation and performance of the anode support for solid polymer electrolyzer(SPE). Mesoporous V-doped TiO2 supports were prepared through Evaporation-Induced Self-Assembly (EISA). By Adams fusion method, nano-sized IrO2 was synthesized at the surface of mesoporous IrO2/Ti(1-x)VxO2（x = 0、0.01、0.05） with certain BET specific surface area. XRD and TEM results show than the phase transition from anatase to rutile structure and gain growth, which took place with Adams fusion, was restricted with V amount. Cyclic voltammetry tests of 40 wt% IrO2 loaded IrO2/Ti(1-x)VxO2（x = 0、0.01、0.05）composite catalysts were carried out in N2-saturated 0.1M HClO4 solution, current density increased obviously with the amount of V, which proves the improvement on OER activity of catalyst by V doping on TiO2 support. Key words: SPE water electrolysis; oxygen evolution reaction; meso-porous TiO2; catalyst support; IrO2 0 引言 氢气作为清洁高效的能量载体受到了全球研究者的关注。氢气可以利用可再生能源转化 而来，其能量也可以通过燃料电池技术再次转化为电能供分布式电网、备用电站以及交通工 具使用[1, 2]。水电解作为制氢的主要途径之一，有着产出过程消除碳排放的重要优势。 近年来基于燃料电池技术发展而来的固体电解质电解器（solid