2024,7075,6063铝合金阳极氧化膜的生长行为和性能的对比研究.docVIP

  Comparative study of growth behavior and characterisation of anodic oxide film on 2024,7075 and 6063 aluminum alloy# Yu Jiayin1, Cui Xinfang2, Qiao Yingjie1** 5 10 15 20 25 30 35 40 (1. School of Materiala Science and Chemical Engineering, Harbin Enigineering University, Harbin 150001; 2. The System Design Insitute of Mechanical Engineering, China Aerospace Science and Industry corporation) Abstract: In the present study, specimens of 2024 and 7075 aluminum alloys as well as 6063 aluminum were anodized in oxalic acid and acetic acid electrolytes. The anodized films were characterized by scanning electron microscopy, optical microscope, and Hysteron Tribo indenter. The results shows that alloy types markedly affect the kinetics of anodizing but the basic aspects of the anodizing mechanism are similar. It is found that the V(t) value decreases suddenly after the voltage reaches the maximum value at the initial stage for 6063 aluminum, but for 7075 and 2024 aluminum alloys, the V(t) values decrease slowly with the time. For alloys under certain anodizing conditions, the anodizing efficiency of 7075 and 2024 alloys were lower than that of 6063 aluminum. With the effect of alloying elements, the anodic film on 2024 and 7075 alloys have lower growth rate and mechanical properties than those of 6063 aluminum. The morphologies of anodic films on 2024 and 7075 alloys show a higher porosity, lots of pits and cavities, which is resulted in their lower mechanical properties. Keywords: Material surface and interface; Aluminum; Anodic oxide film; Growth; Characterisation 0 Introduction There are various alloying elements presented in the aluminum substrate as solid solutions, or second phases, such as zones, precipitates, or intermetallic compounds of various shapes, sizes and compositions[1]. They would have a big influence in film growth, film composition and microstructure during anodization [2,3]. Guminski et al [4] found that Mg2Si, CuAl2, β-AlMg, and CrAl7 particles