聚磷酸胺阻燃聚乙烯的研究.pdfVIP

聚磷酸胺阻燃聚乙烯的研究 摘 要 本文研究了 APP 阻燃 PE 的制备工艺和配方，通过实验，获得了较优的工艺条件。由于 PE 的极限氧指数低(仅为 17. 4 )，极易燃烧，因而对其进行阻燃改性是十分必要的，本文试 验结果得知，通过添加 APP ，提高了PE 的氧指数值，起到了阻燃的效果，并具有较好的性 能。通过实验，比较了在包覆量相同的条件下，加入 APP 对 PE 熔体流动、拉伸强度、断裂 强度、屈服强度、断裂伸长率、氧指数这些性能的影响，得到结论：未包覆 APP 和包覆量 较小（10%）的 APP 加入，使 PE 的熔体流动降低。而包覆量较大（15%、20% ）使 PE 的 熔体流动性上升。对于拉伸强度和屈服强度，加入未包覆的 APP 和包覆量较小（10%）的 APP ，使它们有下降趋势。大包覆量的APP 加入，使 PE 的拉伸强度和屈服强度有上升趋势。 而 APP 的加入对PE 断裂伸长率的影响也较大，总的来说，断裂伸长率是在波动中有上升趋 势。最后，讨论的是氧指数，由于 APP 是阻燃剂，加入后 PE 的氧指数有了一定的提升，实 验表明，在包覆量为 20% 时，阻燃效果最好。 关键词：阻燃，APP，PE，阻燃剂 I Abstract GengGuanYu (Beijing institute of petrochemical technology 102617) This text research making craft and formula of the APP as a flame retardant add to PE, pass experiment, acquired more excellent craft condition. Because PE extreme limit oxygen the index number be low(only is 17. 4), easiest combustion, as a result as to its carry on flame retardant to modified is a necessity very, this text experiment result know, pass to add APP, exaltation PE oxygen index number value, inprove the flame retardancy of PE, and have better function. Pass an experiment, comparison under the condition that pack quantity homology join APP a body to the Melt Flow Index of PE, tensile strength , split strength, yield strength and elongation at break rate, oxygen index number these functions of influence, come to the conclusion: Dont pack the APP with smaller(10%) pack quantity of APP and join, make PE Melt Flow Index lower. But pack quantity more big(15%, 20%) make Melt Flow Index of PE ascension. For tensile strength and yield strength, join dont pack APP and pack smaller(10%) quantity of APP, make them decreased. Big pack quanti