崇明夏季地面高CO浓度的成因分析.doc

  崇明夏季地面高 CO 浓度的成因分析# 何京伟1,2，王聿绚1** （1. 清华大学地球系统科学研究中心，北京 100084； 5 10 15 20 25 30 2. 清华大学环境学院，北京 100084） 摘要：本文利用清华大学崇明站点的 CO 和气象观测资料，分析了 2010 年 8 月崇明 CO 的 变化，结果发现，尽管由于东亚夏季风的影响，崇明 8 月的平均 CO 浓度较低，其月均值是 330 ppb，但有三个时段 CO 的值异常升高，其平均值超过 600 ppb，这三个时段分别是是 1-4 日，12-17 日和 28-30 日。通过 CO 和天气条件的相关性分析，发现崇明的高 CO 与夏季季 风环流密切相关，西太平洋副热带高压变化引起的下沉逆温和受台风影响形成的稳定气层是 造成崇明 CO 浓度增加的气象成因。进一步通过 GEOS-Chem 大气化学传输模式的敏感性试 验，结果指出，8 月 1-4 日和 12-17 日的高 CO 的主要来源是长三角地区人为源的区域排放， 而 8 月 28-30 日的高 CO 主要来源于崇明站点人为源的局地排放。崇明夏季地面 CO 浓度的 异常升高取决于气象条件和排放源的共同作用。 关键词：CO 浓度；气象条件；人为源排放；GEOS-Chem 模式 中图分类号：X131.1 Analysis of high levels of CO at Chongming in summer HE Jingwei1,2, WANG Yuxuan1 (1. Center for Earth System Science,Tsinghua University, Beijing 100084; 2. School of Environment,Tsinghua University, Beijing 100084) Abstract: In this paper the variations of surface CO concentrations in August 2010 at Chongming, a remote rural site northeast of Shanghai founded by Tsinghua University, are analyzed. The results show that although the monthly mean concentrations of CO are low due to East Asia Summer Monsoon, high levels of CO pollution episodes occur during three time periods: 1-4, 12-17 and 28-30 August 2010. The correlation analysis of CO with meteorological parameters indicates that the subsidence flow associated with the West Pacific Subtropical High and the stable layer associated with typhoon are the two meteorological causes of the high CO episodes. Sensitive simulations using the GEOS-Chem chemical transport model indicate that the high CO concentrations during 1-4 and 12-17 Aug originate from regional anthropogenic emissions in the Yangtze Delta Region, while high CO levels during 28-30 August come from local emissions around Chongming. We conclude that abnormally high CO levels at Chongming in August 2010 are caused by the joint influence of anthropogenic emissions and favorable weather conditions. Keywords: CO mixing ratios; Weather conditions; Anthropogenic emissions; GEOS-Chem model 35 0 引言 CO