Nb4Si含量对激光熔覆Ti-Fe合金涂层组织和性能的影响.doc

  Nb4Si 含量对激光熔覆 Ti-Fe 合金涂层组织 和性能的影响 王锐，王存山** 5 10 15 20 25 30 35 40 （大连理工大学三束材料改性教育部重点实验室，辽宁 大连 116023） 摘要：采用激光熔覆技术，在 TA15 钛合金表面制备了具有不同 Nb4Si 添加量的 Ti-Fe 合金 涂层。采用 X 射线衍射仪、扫描电镜、显微硬度计、纳米压痕仪和摩擦磨损试验机，系统 研究了 Nb4Si 含量对合金涂层组织和性能的影响规律。研究结果表明，不同 Nb4Si 含量的 Ti-Fe 合金涂层皆主要是由 β-(TiNb)树枝初晶和 β-(TiNb)+TiFe 共晶组织所构成。但有所不同 的是，随着 Nb4Si 添加量的增加，涂层中共晶组织的数量呈现出先增后减的变化趋势，即在 Nb4Si 添加量为 2.0 at.%时，共晶组织的数量为最多，且在 Nb4Si 的添加量超过 0.5 at.%时， 涂层中开始有少量的 β-Nb5Si3 相形成。由于受共晶组织增强作用的影响，在 Nb4Si 添加量为 2.0 at.%时，合金涂层的硬度、减磨性和耐磨性能为最高，而弹性模量为最低。 关键词：激光熔覆；Ti-Fe 合金；组织；性能 中图分类号：TG178 Influence of Nb4Si content on microstructure and properties of Ti-Fe alloy coating prepared by laser cladding Wang Rui, Wang Cunshan (State key lab for materials modification by laser, ion, and electron beams, dalian University of Technology, Ministry of Education, LiaoNing DaLian 116023) Abstract: Ti-Fe alloy coatings with different Nb4Si additions were prepared by laser cladding on TA15 alloy. The influence of Nb4Si content on microstructures and properties of the coatings were investigated by means of X-ray diffraction, scanning electron microscopy, electron probe microanalyzer, Vickers hardness tester, nano-indenter, and frication wear testing machine. The results show that the coatings with different Nb4Si additions mainly consist of β-(TiNb) dendrite and β-(TiNb)+TiFe eutectic. However，what has changed is that with increasing the Nb4Si addition, the content of the eutectic presents the trend of first increasing then decreasing, namely, the highest value is obtained at 0.2at.% Nb4Si addition. Another change in the microstructure is that a small amount of β-Nb5Si3 phase is formed as the Nb4Si addition is beyond 0.5 at.%. When the Nb4Si addition is 0.2 at.%, the hardness, friction and wear properties of the coatings reach the highest, respectively, while the elastic module is the lowest, as result of high eutectic content. Keywords: Laser cladding; Ti-Fe alloy; Microstructure; Properties 0 引言 钛合金具有密度低、比强度高、耐蚀性和高温性能好等优异性能，在航空航天、国防军 事、