PVA _HA复合水凝胶力学性能分析及有限元模拟.docVIP

  PVA /HA 复合水凝胶力学性能分析及有限 元模拟# 戴祖明，张德坤，陈凯** 5 10 15 20 25 30 35 40 45 （中国矿业大学材料科学与工程学院，江苏 徐州 221116） 摘要：目的 通过实验与有限元模拟对羟基磷灰石(HA)改变聚乙烯醇/羟基磷灰石(PVA/HA) 复合水凝胶的力学性能本质及其承载特性的探究。方法 在 UMT 试验机上开展 PVA/HA 复合水 凝胶的压缩及应力松弛实验。通过模拟与实验结果相结合，研究 PVA/HA 复合水凝胶的承载 特性及 HA 对其性能的影响。结果 随着 HA 含量的增加，PVA/HA 复合水凝胶的压缩模量先增 大后减小，而渗透系数先减小后增大，HA 含量为 3%的 PVA/HA 复合水凝胶压缩模量最大、渗 -15 4 -1 -1 着施载时间的增加呈现先增加后减小的非线性变化，加入 HA 的 PVA/HA 复合水凝胶的液体承 载比例明显增加。应力松弛速率随着 HA 含量增加呈先上升后下降趋势，下压相同位移 HA 含量为 3%时 PVA/HA 复合水凝胶所能分散的应力更多。结论 PVA/HA 复合水凝胶内部的承载 特性影响着其力学性能，HA 含量为 3%时的 PVA/HA 复合水凝胶力学性能最优，更接近于天然 关节软骨的力学性能。 关键词：PVA/HA 复合水凝胶；有限元模拟；力学性能；承载特性 中图分类号：R318.01 Mechanical properties analysis of PVA/HA composite hydrogel and its finite element simulation DAI Zuming, ZHANG Dekun, CHEN Kai (College of Materials Science and Engineering , China University of Mining and Technology, JiangSu XuZhou 221116) Abstract: Objective By means of the finite element simulation, the mechanics performance nature of polyvinyl alcohol/hydroxyapatite(PVA/HA) composite hydrogel through changing the content of hydroxyapatite (HA) and its load-bearing characteristics were studied. Method The compression and stress relaxation tests of PVA/HA composite hydrogel were performed on the UMT test machine. Combining the simulation and experimental results, the load-bearing characteristics of PVA/HA composite hydrogel and the influence of HA to PVA/HA composite hydrogel’s performance were investigated. Results With the increasing of the HA content, the compressive modulus of PVA/HA composite hydrogel first increases and then decreases and its permeability coefficient first decreases and then increases. When the HA content is 3%，the compressive modulus of PVA/HA composite hydrogel is maximum and its permeability coefficient is minimum, which are 1.25 MPa and 1.59×10-15 m4N-1s-1, respectively. The fluid bearing proportion of PVA/HA composite hydrogel first increases and then decreases with the increasing of the loading time, which presents nonlinear change. The pr