水泥水化浆体中C-S-H微结构脱钙分析.docVIP

  水泥水化浆体中 C-S-H 微结构脱钙分析# 何真，王磊* （水资源与水电工程国家重点实验） 5 10 15 20 25 30 35 摘要：本文采用富里埃红外和高分辨的固体魔角旋转核磁共振技术，深入研究了 2 种硅酸盐 水泥水化 3 个龄期浆体中 C-S-H 凝胶的微结构。研究发现：硅酸盐水泥水化生成的 C-S-H， 与矿物 1.4nm-tobermorite 和 jennite 存在的显著结构差异主要表现在结晶性和硅氧四面体聚 合度两个方面；C-S-H 的聚合机理研究表明，水泥水化持续生成的水化硅酸根单体 Q0H 与 质子化后的二聚 C-S-H 发生聚合，形成少量 C-S-H 长链，这是随龄期增加 C-S-H 聚合度升 高的主要原因；同时，C-S-H 中四配位铝(Al[4])出现在桥四面体位置，其作用类似水化硅酸 根单体，桥连二聚 C-S-H 形成更高聚合态的铝硅链。上述研究将为揭示 C-S-H 的微结构及 形成机理提供依据。 关键词：C-S-H；微结构；聚合度；机理；核磁共振 中图分类号：TQ172 The Decalcification Analysis of C-S-H Microstructure in Hydrated Portland Cement Paste hezhen1, wanglei2 (1. State Key Laboratory of Water Resource and Hydropower Engineering Science; 2. State Key Laboratory of Water Resource and Hydropower Engineering Science, Wuhan University, Wuhan 430072) Abstract: Effects of decalcification on microstructure of calcium silicate hydrate (C-S-H gel) in hydrated ASTMⅠcement paste at various ages were studied by X-Ray Fluorescence Spectrometer, X-Ray Diffraction, Fourier Transform Infrared Spectroscopy and 29Si MAS NMR respectively. The results show that the degree of silicate polymerization in C-S-H was largely increased as the bulk C/S molar ratio in the hydrated pastes was reduced from 3.49 to ~1.83 during the leaching process. Both dimeric C-S-H and tobermorite-like C-S-H formed in the paste in which the former dominates was decalcified. Dimeric C-S-H was protonated after the calcium ions in Si-O-Ca bonds of dimers were removed when decalcified ,then Si-OH bonds present. Polymerization between hydrated monomers(Q0H) and dimers with Si-OH resulted in a few longer silicate chains. Decalcification has less effect on the structure of tobermorite-like C-S-H compared with that of dimers, because the central Ca-O layer of tobermorite-like C-S-H was not changed and the tobermorite-like C-S-H was not the dominant phase and had dreierketten of the 3n-1 type. Moreover, tetrahedrally coordinated aluminum ions occupied more bridging sites on tobermorite-like C-S-H when decalcified, t