共模板剂法制备介孔TiO2-Al2O3及其负载NSR催化剂.docVIP

  共模板剂法制备介孔 TiO2-Al2O3 及其负载 NSR 催化剂# 李仲博，孟明** 5 10 15 （天津大学化工学院催化科学与工程系，天津 300072） 摘要：采用非离子型表面活性剂 OP（聚乙二醇辛基苯基醚）和阳离子型表面活性剂 CTAB（十 六烷基三甲基溴化铵）作为共模板剂，将柠檬酸络合与模板剂分解相耦合制备出了介孔 TiO2-Al2O3 及其负载型 NSR 催化剂 Pt/K/TiO2-Al2O3。BET 结果表明，采用共模板剂法制备的 2 2 2 显示，共模板剂法制备的载体负载的 NSR 催化剂中，Pt 的分散性最好，TiO2 的晶粒尺寸最 小，载体的表面总酸量也最大。NOx 储存与抗硫实验结果表明，共模板剂法制得的 Pt/K/TiO2-Al2O3 催化剂具有最大的 NOx 储存量（比传统共沉淀法制备的样品提高了 11.8%）， 以及最佳的硫化再生性能（硫化再生效率达到 94%）。未来随着燃油中硫含量的不断下降， 采用共模板剂法制备的介孔 NSR 催化剂 Pt/K/TiO2-Al2O3 将具有更广泛的应用前景。 关键词：Pt/K/TiO2-Al2O3；OP；CTAB；介孔；NOx 储存；抗硫 中图分类号：O643 文献标识码：A  Preparation of Mesoporous TiO2-Al2O3 and Its Supported 20 25 30 35 40 45 NSR Catalyst by Co-Templates Method Li Zhongbo, Meng Ming (Department of Catalysis Science Technology, School of Chemical Engineering Technology, Tianjin University, TianJin 300072) Abstract: The mesoporous binary oxide supports TiO2-Al2O3 were prepared by citric acid complexation-organic template decomposition method, using the mixture of nonionic p-octyl polyethylene glycol phenyl ether (OP) and cationic cetyltrimethyl-ammonium bromide (CTAB) as co-templates, and the corresponding NOx storage and reduction (NSR) catalysts Pt/K/TiO2-Al2O3 were prepared by using successive impregnation. The results of BET measurement show that the support prepared by using co-templates possesses much larger speci?c surface area (309 m2/g) than those prepared by using single template CTAB (275 m2/g) or by using conventional co-precipitation method (250 m2/g). The structural characterization results of H2-chemisorption, XRD and NH3-TPD indicate that in the corresponding sample the metal Pt possesses the highest dispersion, the TiO2 crystallites show the smallest sizes and the support shows the largest amount of acidity. The results of NOx storage capacity measurement show that the catalyst with the support prepared by co-templates possesses much higher NOx storage capacity than other samples. Although the sulfation treatment decreases the NOx storage property of the catal