水钠锰矿结构变化对对苯二酚腐殖化程度和速率的影响.docVIP

  水钠锰矿结构变化对对苯二酚腐殖化程度 和速率的影响# 曹星辉，刘名茗，冯雄汉，谭文峰，刘凡** 5 10 15 20 25 30 35 40 （华中农业大学资源与环境学院） 摘要：本文以不同浓度焦磷酸钠处理的酸性和碱性水钠锰矿为氧化剂，探讨了水钠锰矿矿物 类型，表面化学性质和亚结构变化，如锰氧化度、八面体空位、层间 H+和 Mn3+对对苯二 酚腐殖化程度和速率的影响。结果表明，酸性水钠锰矿比碱性水钠锰矿具有更高的氧化容量， 这主要归因于酸性水钠锰矿具有更多的层间水合 H+离子和更大的比表面积。以焦磷酸钠络 合出部分层间 Mn3+后，水钠锰矿锰平均氧化度升高，其催化氧化对苯二酚腐殖化的程度有 所增加，Mn2+的释放量减少。此外，焦磷酸钠将水钠锰矿八面体空位上方或下方的部分 Mn3+提取出来后，层间 Mn3+的量减少，对苯二酚腐殖化速率和 Mn2+的释放速率均有所降 低。总的来说，层间 H+对对苯二酚腐殖化程度的影响大于锰平均氧化度，Mn3+对对苯二酚 腐殖化速率的影响大于八面体空位。 关键词：水钠锰矿，对苯二酚，腐殖化，催化氧化，锰氧化度 中图分类号：P578.4，S153.6+22 Mineral structural influence on the degree and rate of humification of hydroquinone catalyzed by birnessites Cao Xinhui, Liu Mingming, Feng Xionghan, Tan Wenfeng, Liu Fan (College of Resources and Environment, Huazhong Agricultural University) Abstract: In this paper, hexagonal and triclinic birnessites synthesized in acidic and alkali media, were treated with differnent concentration of Na4P2O7, and used to study the influence of mineral structure and surface property of birnessites (the average oxidation state (AOS), vacant octahedral site, the interlayer hydrated H+ and Mn3+) on the degree and rate of humification of hydroquinone. The results showed that H-birnessite had higher oxidation capacity than OH-birnessite due to its more interlayer hydrated H+ and larger surface area. The degree of humification of hydroquinone increased, and the amounts of Mn2+ released to the solution decreased with the increase of the average oxidation states owing to the complexation of the interlayer Mn3+ by Na4P2O7. The rate of the humification of hydroquinone and the release of Mn2+ decreased with the decrease of Mn3+ due to the complex reaction between the interlayer Mn3+ and Na4P2O7. The interlayer hydrated H+ had greater influence on the humification degree than the AOS of Mn. The interlayer Mn3+ had greater influence on the humification rate than the vacant octahedral site. Key words: birnessite, hydroquinone, humification, catalytic oxidation, average oxidation state 0 引言 氧化锰矿物是土