熔盐作用下水稻秸秆热解特性研究.docVIP

  熔盐作用下水稻秸秆热解特性研究# 高明辉1,2，姬登祥1,2，于凤文1,2，艾宁1,2，姜洪涛1,2，计建炳1,2** （1. 浙江工业大学化学工程与材料学院； 5 10 15 20 25 30 35 40 2. 浙江省生物燃料利用技术研究重点实验室，杭州 310014） 摘要：为研究水稻秸秆在熔盐作用下的热裂解特性，采用热重分析法考察了 Na+、K+等阳离 子和 Cl-、CO32-、SO42-等阴离子对热裂解行为的影响，并采用 FWO 方法计算了热裂解过程 活化能。研究表明，秸秆主要热解区间为 200～400，随着升温速率升高，热解过程出现“滞 后”现象，最大失重速率增加；相同阳离子条件下，CO32-能促进热解向低温区进行，有利于 挥发分的析出，SO42-固定炭的能力较强；相同阴离子条件下，K+同样较 Na+有利于固定炭的 生成；样品经扣除添加剂之后采用 FWO 方法进行动力学分析，经 NaCl、Na2SO4 和 KCl 处 理的样品降低了原样品活化能，经 Na2CO3 处理过样品活化能有所增加。研究为农林废弃物 等生物质资源的开发利用方法提供一定的参考。 关键词：水稻秸秆；熔盐；热重分析；FWO；动力学分析 中图分类号：TK6 Study on the pyrolysis characteristics of rice straw treated by molten salts GAO Minghui1,2, JI Dengxiang1,2, YU Fengwen1,2, AI Ning1,2, JIANG Hongtao1,2, JI Jianbing1,2 (1. College of Chemical Engineering and Materials Science,Zhejiang University of Technology; 2. Zhejiang Province Key Laboratory of Biofuel, Hangzhou 310014) Abstract: To investigate the effect of molten salts on pyrolysis characteristics of rice straw, the pyrolysis behaviors of rice straw prepared by the cations Na+、K+ and the anions Cl-、CO32- and SO42- have been investigated by means of thermogravimetric analysis. The results indicated that the pyrolysis of rice straw was mainly in the range of 200℃and 400℃.With the increase of heating rate, hysteresis was occurred on the pyrolysis process, and the maximum weight lose rate increased. pyrolysis happened at a lower temperature area and the volatile matter vapored easier under the influence of CO32-, and SO42- had benefits on fixing carbon under the same cation condition. Comparing with Na+, K+ was easier for the generation of fix carbon under the same anion condition. Integration method FWO was used in kinetic analysis on the samples processed by deducting the additive salts, the results showed that the activation energy of rice straw processed by NaCl、Na2SO4 and KCl decreased compared with the original sample, but to the opposite , the activation energy processed by Na2CO3 increased. This research can provide a certain referen