石墨烯用作锂离子电池负极材料的电化学性能研究.docVIP

  石墨烯用作锂离子电池负极材料的电化学 性能研究 高云雷，赵东林，白利忠，张霁明，张凡，谢卫刚 （北京化工大学化工资源有效利用国家重点实验室，碳纤维及功能高分子教育部重点实验 室，北京 100029） 摘要：以天然鳞片石墨为原料，通过氧化、离心分离、低温氢气还原和超声分散处理制备了 高品质的石墨烯片（1~4 层）。采用透射电镜（TEM）、高分辨透射电镜（HRTEM）、傅里叶 变换红外光谱（FT-IR）、拉曼光谱、X-射线衍射（XRD）等测试方法对石墨烯的结构和形貌 进行了研究。通过恒流充放电、循环伏安法（CV）和交流阻抗（EIS）等手段研究了石墨烯 用作锂离子电池负极材料的电化学性能。结果表明在 0.2 mA/cm2 的电流密度下石墨烯首次 可逆比容量为 1005 mAh/g，经过 30 个循环后放电比容量保持在 609 mAh/g，在大电流密度 下放电容量仍然能保持 576 mAh/g，表明石墨烯负极材料具有优异的倍率性能。 关键词：石墨烯；电化学性能；锂离子电池；负极材料 中图分类号：O613.71；O646 文献标识码：A  Electrochemical performance of graphene sheets as anode material for lithium-ion batteries Gao Yunlei, Zhao Donglin, Bai Lizhong, Zhang Jiming, Zhang Fan, Xie Weigang (State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China) Abstract: High quality graphene sheets with a curled morphology consisting of a thin wrinkled paper-like structure and fewer layers (1~4 layers) has been prepared from natural graphite by oxidation, hydrogen reduction at 400??C and ultrasonic treatment. Graphene sheets were investigated as anode materials for lithium ion batteries by transmission electron microscopy (TEM), high-resolution TEM, X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy and a variety of electrochemical testing techniques. The electrochemical performance testing results showed that the first reversible specific capacity of the graphene sheet electrode was as high as 1005 mAh/g at a current density of 0.2 mA/cm2. After 30 cycles the reversible specific capacity was still maintained at 609 mAh/g. Even at a high current density of 1 mA/cm2, the reversible specific capacity remained at 576 mAh/g after 30 cycles. These results indicate that the prepared high quality graphene sheets possess excellent electrochemical performances for lithium storage. Key words：graphene sheets; electrochemical performance; lithium ion batteries; anode materia