钾长石KAlSi3O8-CaO-Fe2O3-CaF2体系烧结复合铁酸钙生成的固相反应特性研究.doc

钾长石KAlSi3O8-CaO-Fe2O3-CaF2体系烧结复合铁酸钙生成的 固相反应特性研究 摘 要 白云鄂博矿矿物同时含有F、K、Na等有害元素，属于世界独有的特殊矿石，一方面其中的SiO2和Al2O3脉石主要以含K、Na的复合硅酸盐和硅铝酸盐形态存在，如: 钾长石（KAlSi3O8）、钠辉石（NaFeSi2O6）另一方面CaF2可参与枪晶石3CaO·2 SiO2·CaF2的生成反应，抑制铁酸钙生成。这就使得白云鄂博矿烧结复合铁酸钙的生成机理变得十分复杂，探明白云鄂博特殊矿烧结复合铁酸钙生成机理这个科学问题，可为包钢烧结技术进步提供重要的理论依据。本论文采用差热分析（DSC）和X射线衍射(XRD)的实验方法，对KAlSi3O8CaO-Fe2O3-CaF2体系可能产生的固相反应进行系统研究，探明固相反应产物及出现产物的开始温度，以揭示特殊矿烧结复合铁酸钙生成的固相反应特性及其对复合铁酸钙生成的影响机理。 关键词：钾长石；固相反应；烧结；复合铁酸钙；生成机理 he solid-phrase reaction characteristic of KAlSi3O8-CaO-Fe2O3-CaF2 system sintered with calcium ferrite Abstract The mineral in the Iron mine of Baiyun Obo contains harmful elements such as F、K、Na, which is unique to other iron ore in the world ,on one hand, SiO2 gangue and Al2O3 gangue in it exist in the form of complex Silicate , Alumina and Silicate such as KAlSi3O8，NaFeSi2O6,on the other hand , CaF2 can involve in reaction which generate 3CaO·2 SiO2·CaF2 inhibiting the formation of Calcium ferrite. This makes the mechanism of the Calcium ferrite matrix composites’formation very complex in the iron mine of Bayan Obo, exploring the mechanism of the unique Calcium ferrite matrix composites’ formation can provide theoretical basis for the development of sintering in baogang. This issue carries out systematic research on system of KAlSi3O8-CaO-Fe2O3-CaF2 which may generate solid state reaction, combining the experimental Methods of DSC and XRD, in order to Verify the product of solid state reactionand the starting temperature when the product appear, and to explore characteristics of solid-state reaction in the formation of unique Iron ore sintering composite calcium and how it affect the mechanism of the compound Calcium ferrite. Keywords: K-feldspar;solid-state reaction;sintering;SFCA;Generating mechanism 目录摘 要 I Abstract II 第一章 文献综述 1 1.1研究背景 1 1.2钾长石物理及化学性质 2 1.3烧结基础特性 3 1.3.1影响同化性的因素 3 1.3.2影响液相流动性的因素 4 1.3.3铁酸钙的生成特性 6 1.3.4影响铁酸钙生成的因素 8 1.4烧结固相反应 12 1.4.1有关固相反应的研究内容及研究方法 12 1.5本实验采用的方案 15 第二章 实验方案 16 2.1研究内容 16 2.2研究方法 16 2.2.1 四个体系