聚氨酯胶粘剂的制备、性能及其交联改性研究.pdfVIP

·38 · 材料导报网刊 2007 年第2 卷第1 期 聚氨酯胶粘剂的制备、性能及其交联改性研究* 1 2 1 杨冬亚 ，邱凤仙，曹国荣 ，吕杰 (1 江苏大学化学化工学院，镇江 212013; 2 江苏大学理学院，镇江 212013) 摘要 以聚醚多元醇（GE210）、1，4 一丁二醇和甲苯-2，4-二异氰酸酯 (TDI)等为原料，以聚酯多元醇(P210)为交联 剂，合成了具有不同异氰酸酯指数（R 值）的线型和交联型两类溶剂型聚氨酯胶粘剂。通过红外谱图（FT-IR）表征了聚氨 酯的结构，测定了所合成的聚氨酯胶粘剂的物理性能及其对皮革基材的粘接性能。结果表明，线型聚氨酯胶粘剂对皮革具有 较强的粘接强度，且随着异氰酸酯指数的增加，粘接强度逐渐增强。加入交联剂后，随R 值增大，胶粘剂的粘接强度也逐渐 增大。在相同R 值的情况下，交联型聚氨酯胶粘剂比线型聚氨酯胶粘剂的粘接强度有较大程度的提高。 关键词 聚氨酯 胶粘剂 粘接强度 交联剂 Preparation and Characterization of Polyurethane Adhesives and Their Crosslinking Modification 1 1 2 1 YANG Dongya , QIU Fengxian , CAO Guorong , LV Jie (1.School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 ；2 Faculty of Science , Jiangsu University, Zhenjiang 212013) Abstract The solvent polyurethane adhesives based on polyether polyol (GE210), toluene diisocyanate(TDI), polyester polyol crosslinking agent (P210) and 1,4-butanediol are prepared in this article. Their structures are characterized by FT-IR. The physical properties of these polyurethane samples with different ratio of NCO/OH and chain extender are further measured. The results indicate that all the monomers are exhausted after certain time. The polyurethane adhesives possess good binding strength to leather, which enhances with the increasing of the isocyanate index. Meanwhile, the binding strength of crosslinked polyurethane adhesives is better than that of the linear adhesives. Key words polyurethane, adhesive, binding strength, crosslinking agent 聚氨酯是一种含软链段和硬链段的嵌段共聚物，软段由 公司ATAVAR360