无机硅铝聚合材料（地聚物）的制备及其电池隔膜应用研究.pdfVIP

34 材料导报网刊 2009 年12 月第4 卷第4 期 无机硅铝聚合材料（地聚物）的制备及其电池隔膜应用研究 陈足意，周德璧，伍绍飞，时一方 （中南大学化学化工学院，长沙 410083 ） 摘要 地聚物是以SiO 、Al O 为主要成分，具有三维网状结构的无机凝胶材料。研究制备了地聚物材料，将其应用 2 2 3 于碱性电池隔膜。结果表明，将高岭土在 800 ℃烧煅5h 得到的偏高岭土，与氢氧化钠、二氧化硅以质量比 5.0 2.0 1.5 均 混合, 然后在 60℃养护 6h，制得的地聚物显示出良好的力学强度和离子导电性能。以此地聚物作为隔膜，组装了小型锌空 气电池，并测试了其放电性能。 关键词 地聚物 碱激发 氢氧化钠 电池隔膜 Study of Preparation of Inorganic Polymer Si-Al Material (Geopolymer ) and Its Application as Separator in Alkaline Battery CHEN Zuyi, ZHOU Debi, WU Shaofei, SHI Yifang (College of Chemistry and Chemical Engineering, Central South University, Changsha 410083) Abstract Geopolymer is an inorganic cementing material which mainly consists of SiO and Al O with a 2 2 3 three-dimensional network structure. Investigation is carried our in this work to prepare this material for using as separator material in alkaline battery. The geopolymer is prepered by calcinating the powder of kaoline at 800℃ for 5 hours; then mixing the metakaolin obtained with sodium hydroxide and silica at the mass ratio of 5.0 2.0 1.5; and then conservating the mixture at 60℃ for 6 hours. The prepared geopolymer shows good mechanical strength and good ionic conductivity. A small zinc-air battery with the geopolymer as separator is assembled and tested for its discharging performance. Key words geopolymer, alkali-activated, sodium hydroxide, battery separator 20 世纪70 年代末，法国的J . Davidovits 等用碱激发偏 1.3 地聚物的制备 高岭土形成了一类新型碱胶凝材料，并称其为地聚物 首先将氢氧化钠固体 1.5g、1.8g、2.0g、2.3g、2.5g） [1,2] Geopolymer ） 。它以SiO 、Al O 四面体为主要组成， 2 2 3