SHS法制备AlN粉体的研究.pdfVIP

·28 · 材料导报网刊 2006 年 8 月第 4 期 SHS 法制备 AlN 粉体的研究 李家科，周健儿，刘 欣，范学运，熊 昆 （景德镇陶瓷学院材料科学与工程学院，江西 333001 ） 摘要 以Al,N 为合成原料，以AlN 为稀释剂，NH F 为燃烧调节剂，采用SHS（Self-propagating High-temperature Synthesis ） 2 4 法合成 AlN 粉体，实验系统地研究了稀释剂含量、燃烧调节剂含量、N2 压力等因素对 AlN 合成率和粒径的影响。结果表明： 在稀释剂 AlN 外加量为 40% ，燃烧调节剂NH F 外加量为 5%, ，N 压力为 8MPa 条件下，AlN 合成率为 100%，粉体的平均 4 2 粒径小于 2µm 。采用XRD 、SEM、XDC 等检测手段对粉体的物相组成和形貌进行表征，揭示了粉体性能与工艺因素之间的 关系。 关键词 SHS 法 AlN 粉体 合成率 稀释剂 燃烧调节剂 Study on Preparation of AlN Powder by SHS Method LI Jiake, ZHOU Jianer, LIU Xin, FAN Xueyun, XIONG Kun (School of Materials Science and Engineering, Jingdezhen Ceramic Institute , Jiangxi 333001) Abstract AlN powder is prepared by SHS method using Al ,N as main materials ,and using AlN as diluent, NH F as 2 4 combustion-adjustment agent .The effects of diluent content , combustion-adjustment agent content and N2 pressure on synthetic ratio and particle size of AlN powder are studied. The results show that when diluent adding content being 40%, combustion- adjustment agent adding content being 5%,and N2 pressure being 8MPa, synthetic ratio of AlN amounts to 100%,and mean particle size of AlN is less than 2µm. Phase composition and morphology of synthetic powder are investigated by XRD, SEM, XDC,ect. Relationship between synthetic powder performances and technology factors are studied. Key words SHS method ,AlN powder,synthetic ratio, diluent, combustion-adjustment agent 自蔓延高温合成（Self-propagating