联咪唑-羧酸双配体构筑的金属-有机配位聚合物的合成化学论文.doc

江西师范大学 本科毕业论文 PAGE 1 - 本科毕业论文 联咪唑-羧酸双配体构筑的金属-有机配位聚合物的合成 Sythesis of metal-organic coordination polymers constructed from biimidazole and carboxylic acid ligands 姓 名: 学 号： 指导老师： 学 院： 专 业：化学教育 完成时间： 摘要 近年来，金属-有机配位聚合物晶体材料的设计、合成、结构及性能研究备受关注。这些配位聚合物不仅具有新颖的拓扑结构，而且在催化、医药、光电、磁性及多孔材料等方面展现了广阔的应用前景。因此，研究配位聚合物的合成与晶体结构，可为设计和合成各种配位聚合物功能材料提供切实可行的途径和可靠的理论依据。本论文以多功能的均苯三甲酸(H3btc)和联咪唑(Bimz)为有机构筑块与过渡金属离子Zn2+在水热条件下组装配位聚合物晶体，并成功合成了一个配合物[Zn2(Hbtc)2(Bimz)2]，利用X-射线单晶衍射和红外光谱对该配合物的结构进行了表征，该配合物为双核结构，并通过N-H…O和O-H…O氢键作用构成三维的超分子。 关键词：金属-有机配位聚合物、合成、晶体结构 Abstract In resent years, much attention has been paid to the design, synthesis, crystal structures and properties of metal-organic coordination polymers (MOCPs), which is not only driven by the intriguing topological structure of the MOCPs, but driven by the extensively potential applications in the fields such as catalysis, medicine, opto-electronic, magnetic and porous materials. So, it is important to explore the synthesis, crystal structures, and relations of structures and properties of the MOCPs. In this thesis, we have synthesized the MOCPs crystals by hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3btc) , 2,2-biimidazole (Bimz) and Zn(II) ions, and successfully obtained a coordination compound [Zn2(Hbtc)2(Bimz)2], which characterized by single crystal X-ray diffraction and infrared spectrum. The compound [Zn2(Hbtc)2(Bimz)2] features a binuclear structure, which is further extended a supermolecular structure through the N-H…O and O-H…O hydrogen bonds. Key words： Metal-organic coordination polymer; HYPERLINK dict://key.0895DFE8DB67F9409DB285590D870EDD/synthetize \o 查找: synthetize synthesis; crystal structure 目录 中文摘要……………………………………………………..…..…..Ⅰ Abstract………………………………………………………..……..Ⅱ 目录 1 前言………………………………………………………….……...1 1.1 金属-有机配位聚合物概念………………………………..…..…1 1.2金属-有机配位聚合物的合成方法………………………..…...…2 1.3羧酸类配体和联咪唑配体的研究意义和应用……………...…5 1.4 本论文的研究内容和方