年产1500吨CEVA工艺设计计算书.docVIP

年产1500吨CEVA工艺设计 摘 要 CEVA是氯化乙烯—醋酸乙烯共聚物，它由EVA氯化制得，是20世纪80年代发展起来的新型高分子材料。目前，我国主要是采用四氯化碳作为氯化反应溶剂的溶剂法生产CEVA。但四氯化碳污染环境，因而其应用受到《蒙特利尔议定书》的限制。因此，研究非溶剂法生产CEVA的生产技术极其重要。 本设计综合环境保护、能源节约及降低成本等角度，选择水相悬浮法生产CEVA。水相悬浮法在国外技术已日趋成熟，并且由于该法不使用有机溶剂，流程短，成本低，且环境污染小，因此发展前景良好。但该法需要解决设备腐蚀以及三废处理的问题。 本设计通过对反应原理以及水相悬浮法生产工艺的分析，确定了年产1500吨CEVA的简要工艺流程，并根据绘图标准，绘制了带控制点的分散工艺流程图以及氯化工艺流程图。同时，按照工艺流程，综合安全及操作方便等因素，利用AutoCAD2004绘制了厂房布置图。通过进行物料衡算和热量衡算，确定了主要设备的尺寸及型号，绘制了氯化反应釜和钛管浮头式换热器结构图。 关键词 CEVA；水相悬浮法；合成原理；工艺设计 The CEVA process design with an annual output of 1500 tons Abstract The Chinese name of CEVA is vinyl chloride-vinyl acetate copolymer, and its prepared by the chlorinated EVA. CEVA is a kind of new polymer materials that develops up from the 1980s. At present, our country is mainly used carbon tetrachloride as a solvent of the chlorinated solvent production of the CEVA. However, carbon tetrachloride pollute the environment, and thus, its application is limited by the Montreal Protocol. Therefore, study on the non-solvent method of CEVA production technology is extremely important. In this design, I take environment protection, energy savings and lower cost into consideration, and finally select the aqueous suspension to produce the CEVA. The technology of aqueous suspension in the foreign has become increasingly mature, and because this method does not use organic solvents, the process is short, the cost is low, the pollution to the environment is little, development of this method has good prospects. But, this method needs to solve the problems of equipment corrosion and waste disposal. Based on the analysis of the principle as well as the production process of aqueous suspension method, the design identifies the brief process of an annual output of 1500 tons CEVA. And according to the drawing standards, I draw the flow diagram of the dispersion process and chlorination process with control points. And then, in accordance with the process, considering the safety opera