以含有乙烯基的硅烷合成SiOC纤维毕业论文.doc

以含有乙烯基的硅烷合成SiOC纤维 摘 要 溶胶-凝胶（Sol-Gel）法具有以下优点：产物结构均匀、高纯，反应温度低，烧结温度比传统温度低400-500 ?C，且成本相对较低。鉴于Sol-Gel法的优势，利用该方法制备出SiOC陶瓷纤维有着重要的意义。这对于硅氧碳纤维的大量生产和应用有着重大的价值。 以正硅酸乙酯（TEOS）和乙烯基三甲氧基硅烷（VTMS）为原料，在催化剂作用下，经交联、纺丝、Ar气保护下热解可以得到致密且直径较小的SiOC陶瓷纤维。通过分析硅氧碳纤维的SEM图片，可以发现所得的纤维直径为20?m左右，且纤维表面致密光滑。通过XRD可以看出，SiOC纤维是无定形态的。通过TG/DSC可以发现，SiOC陶瓷纤维在850-1400 ?C稳定存在。 关键词：溶胶-凝胶法；SiOC陶瓷纤维；交联；VTMS Prepartion of SiOC ceramics fibers from the organosilicon with Vinyl ABSTRACT Sol-Gel method has the following advantages: a product of uniform structure, high purity, low reaction temperature, the sintering temperature of the product lower than conventional method for 400~500 ?C and lower cost. For the advantages of Sol-Gel method, using the method to prepare SiOC ceramics fibers is significant. For mass production and application of SiOC ceramics fibers, it would be and of great value. SiOC ceremics fibers with a small diameter and dense structure can be prepared from TEOS and vinyl trimethoxysilane (VTMS) after cross-linking, spinning, pyrolysis at 1000 ?C using Ar gas as protection gas. The SEM images of SiOC fibers show that the fibers are about 20 ?m in diameter and sense. The XRD spectrum of SiOC ceramics fibers indicate the fibers amorphous. Through the TG curve of gel , the SiOC ceramics fibers are stable between 850 ?C and 1400 ?C Key word: Sol-Gel method; SiOC ceramics fibers; cross-linking;VTMS 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc232584218 第一章 前 言 PAGEREF _Toc232584218 \h 1 HYPERLINK \l _Toc232584219 1.1陶瓷纤维概述 PAGEREF _Toc232584219 \h 1 HYPERLINK \l _Toc232584220 1.2硅氧碳纤维的提出 PAGEREF _Toc232584220 \h 1 HYPERLINK \l _Toc232584221 1.3有机先驱体法制备Si(M)OC纤维 PAGEREF _Toc232584221 \h 3 HYPERLINK \l _Toc232584222 1.4 溶胶-凝胶法制备Si(M)OC纤维 PAGEREF _Toc232584222 \h 4 HYPERLINK \l _Toc232584223 1.5溶胶-凝胶法制备纤维的基本工艺原理 PAGEREF _Toc232584223 \h 7 HYPERLINK \l _Toc232584224 1.6课题的提出 PAGEREF _Toc232584224 \h 9 HYPERLINK \l _Toc232584225 第二章 实验过程 PAGEREF _Toc232584225 \h 9 HYPERLINK \l _Toc23258