毕业论文--微量硼对1Cr17铁素体不锈钢在混酸介质中的腐蚀行为的影响.doc

PAGE 毕业设计(论文) 题 目 微量硼对1Cr17不锈钢在混合酸HHS介质中 腐蚀行为的影响 摘 要 本课题利用真空感应炉冶炼了不含硼和硼质量分数分别为15ppm、21ppm、28ppm的四组1Cr17铁素体不锈钢，主要研究微量硼元素含量变化对铸态铁素体不锈钢1Cr17腐蚀行为的影响。本试验用10×10×6mm的腐蚀试样，采用化学浸泡法和塔菲尔极化曲线法研究了三种试验不锈钢在（3.2%HCl＋3.8%HNO3）介质中的耐蚀性能。试验结果表明：铸态1Cr17铁素体不锈钢在混酸介质中的腐蚀形式为全面腐蚀加晶间腐蚀，不含硼材料主要发生了全面腐蚀;含硼材料主要发生了晶间腐蚀。且随着含硼量的增加，晶间腐蚀越严重,铁素体不锈钢钝化能力增强。对于同一种介质，随着温度的升高，腐蚀速率增大，材料的耐腐蚀性下降。 关键词：铁素体不锈钢，硼含量，耐蚀性 ABSTRACT The subject of the use of vacuum induction furnace smelting boron and boron mass fraction to 15ppm, 21ppm, 28ppm of four sets of the 1Cr17 ferritic stainless steel, the main trace element boron content on the corrosion behavior of cast ferritic stainless steel 1Cr17 . In this experiment, the corrosion specimens of 10 × 10 × 6mm, chemical immersion and Tafel polarization curves of three test the corrosion resistance of stainless steel (3.2% HCl +3.8% HNO3) media. The results show that: the cast state 1Cr17 iron pigment body of stainless steel in the mixed acid media corrosion form of general corrosion plus intergranular corrosion of boron join to improve the 1Cr17 stainless steel resistant to intergranular corrosion can, and with increasing boron content, resistance to intergranular corrosion ability, resistance to full corrosion capacity. KEY WORDS: stainless steel，boron content，corrosion resistance 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc327190553 摘 要 PAGEREF _Toc327190553 \h I HYPERLINK \l _Toc327190554 ABSTRACT PAGEREF _Toc327190554 \h II HYPERLINK \l _Toc327190555 第一章 综述 PAGEREF _Toc327190555 \h 1 HYPERLINK \l _Toc327190556 1.1 课题意义 PAGEREF _Toc327190556 \h 1 HYPERLINK \l _Toc327190557 1.2 铁素体不锈钢组织特征及性能特点 PAGEREF _Toc327190557 \h 1 HYPERLINK \l _Toc327190558 1.2.1 1Cr17铁素体不锈钢组织特征 PAGEREF _Toc327190558 \h 1 HYPERLINK \l _Toc327190559 1.2.2 1Cr17铁素体不锈钢性能特点 PAGEREF _Toc327190559 \h 1 HYPERLINK \l _Toc327190560 1.3 铁素体不锈钢腐蚀类型、腐蚀机理及影响因素 PAGEREF _Toc327190560 \h 2 HYPERLINK \l _Toc327190561 1.3.1铁素体不锈钢腐蚀类型 PAGEREF _Toc327190561 \h 2 HYPERLINK \l _Toc327190562 1.3.2铁素