稠油含氧催化剂的合成与分析论文.doc

稠油含氧催化剂的合成与分析 摘 要 本文以VA 族金属氧化物的有机化合物[ ( Bi2O3 ) ( acac) 2 ]为催化剂，以双氧水做氧化剂，磷酸为质子供体研究了对稠油粘度及酸值的影响，实验测试了反应温度、时间以及催化剂用量对稠油粘度和酸值的改变程度。结果表明, [ ( Bi2O3 ) ( acac) 2 ]对稠油的氧化降粘作用与[ ( Bi2O3 ) ( acac) 2 ]的 浓度、反应温度以及反应时间有关。[ ( Bi2O3 ) ( acac) 2 ]在低温条件下通过降解沥青质来有效降低稠油粘度, 使稠油粘度大幅度下降。稠油中的沥青质减少主要生成胶质、芳烃和饱和烃, 能使酸价从1.74mgKOH/g油增加到9.22mgKOH/g油，这种理化性质的改变促进了稠油体系的稳定, 对稠油开采、运输以及后处理工艺将起到推动作用。 关键字：稠油；降粘；催化氧化降解；酸值 Abstract This paper use organic compounds of the VA group metal oxide (Bi2O3) (acac) 2] as a catalyst, hydrogen peroxide and phosphoric acid as a proton donor to study the impact of heavy oil viscosity and acid number, experimental test of the reaction temperature, time and amount of catalyst on the degree of change of the heavy oil viscosity and acid number. The results show that the (Bi2O3) (acac) 2] and [(Bi2O3) (acac) 2] concentration of the oxidation of the viscosity of heavy oil, reaction temperature and reaction time-related. (Bi2O3) (acac) 2] at low temperatures through the degradation of asphaltenes to effectively reduce the viscosity, the viscosity is a significant decline. Heavy oil asphaltenes decrease was primarily to generate glial, aromatics and saturated hydrocarbons, make the acid value increased from 1.74mgKOH / g oil to 9.22mgKOH/ g oil , changes in such physical and chemical properties for the stability of the system of heavy oil, heavy oil recovery, transportation and post-processing technology will play a catalytic role. Keywords: heavy oil; viscosity reduction; oxidation degradation; acid value 目录 TOC \o 1-3 \h \u HYPERLINK \l _Toc21060 1绪论 PAGEREF _Toc21060 1 HYPERLINK \l _Toc26065 1.1影响稠油流动性的因素 PAGEREF _Toc26065 2 HYPERLINK \l _Toc10927 1.1.1 蜡含量对稠油的影响 PAGEREF _Toc10927 3 HYPERLINK \l _Toc15351 1.1.2 沥青质对稠油的影响 PAGEREF _Toc15351 3 HYPERLINK \l _Toc3371 1.1.3 胶质对稠油粘度的影响 PAGEREF _Toc3371 4 HYPERLINK \l _Toc23644 1.1.4 沥青质的胶体结构及其与胶质的相互作用对稠油的影响 PAGEREF _Toc23644 4 HYPERLINK \l _Toc28818 1.2 稠油开采基础理论 PAGEREF _Toc28818 5 HYPERLINK \l _Toc41