热降解动力学方法研究ABS 的降解机理.pdfVIP

24 7 Vol.24, No.7 2010 7 CHINA PLASTICS July, 2010 ABS 杨有财, 李荣勋, 刘光烨 ( , 266042) : , ( TGA) - - ( ABS) , FlynnWallOzawa issinger , ABS 2 ,350~ 450 , , (E a ) 200 kJ/ mol ,80 %~ 90 % , E 262.81 kJ/mol;500~ 600 , E 130 kJ/mol , a a ABS 0. 946, , ABS , , , : - - ; ; ; ; ; : TQ325.2 : B : 2010 Degradation Mechanism of ABSby Thermal Degradation Kinetics YANG Youcai, LI Rongxun, LIU Guangye ( Engineering Research Center of High Performance Polymer and Molding T echnology, Ministry of Education, Qingdao University of Science and Technology, Qingdao 266042, China) Abstract:In air atmosphere, the mass loss of ABS resin at different heating rates was investigated using T GA. T he kinetics of thermal degradation was described using FlynnWallOzawa and issinger methods. It showed that there weretwo degradation stages. The first stage between 350 a and 450 was the rapid degradation with activation energy ( E ) about 200 kJ/ mol; the cross linking reaction coupled with the degradation. When the mass loss in the range of 80 %~ 90 %, char formation was observed with Ea increasing to 262. 81 kJ/ mol. T he second stage was the oxidation of carbon with E a decreasing to 130 kJ/ mol, so the carbon had a poor thermal stability. T he reaction order of ABS thermal degradation was found to be 0.946, so the mechanism of ABS thermal degradation was controlled by the processes of random nuclear formation and growth. The thermal degradation occ