海南柏木阴沉木挥发油的化学成分分析及耐腐性研究.pdfVIP

海南柏木阴沉木挥发油的化学成分分析及 耐腐性研究 严宗达,卢圣楼,郭飞燕,阎瑾,何光鸿,王博云, * 周占胜,周志斌,刘 红 ,于长江 (海南师范大学化学与化工学院,热带药用植物化学省部共建 教育部重点实验室, 海南 海口571158) 摘摇 要:摇 采用GC-MS法对海南柏木阴沉木挥发油的化学成分进行了分析,共分离出56 个色谱 YAN Zong鄄da摇 摇 峰,鉴定出39种化合物,占总离子流出峰面积的91.843%。 应用色谱峰面积归一法分析各成分的 质量分数,GC含量较高的物质有:柏木醇(23.516%)、邻苯二甲酸(11.843%)、D-柠檬烯(10.103%)、邻苯二甲酸二 丁酯(9.843%)和苯酚(5.324 %)等。 耐腐性试验结果表明,海南柏木阴沉木对密粘褶菌(Gloeophyllum trabeum Murr.) 和彩绒革盖菌(Coriolus versicolor Quel)具有较好的耐腐性(木材平均质量损失率:基部4.365%,中部4.58%)。 关键词:摇 阴沉木;挥发油;化学成分;耐腐性 中图分类号:TQ35摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 文章编号:0253-2417(2012)05-0111-04 Chemical Composition and Corrosion Resistance of the Essential Oil from Buried Wood of Hainan Cypress YAN Zong鄄da,LU Sheng鄄lou,GUO Fei鄄yan,YANJin,HE Guang鄄hong,WANG Bo鄄yun, ZHOU Zhan鄄sheng,ZHOU Zhi鄄bin,LIU Hong,YU Chang鄄jiang (College of Chemistry and Chemical Engineering,Hainan Normal University;Key Laboratory of Tropical Medicinal Plant Chemistry of Ministry of Education,Haikou571158,China) Abstract:Thechemicalconstituentsofessentialoilfromburiedwoodof HainanCypresswereseparatedandidentifiedby GC鄄MS. Relative contents of essentialoilweredeterminedbypeakareanormalization. 39 compoundsfromtheessentialoilwereseparated and identified,which account for 91.843 % of total essential oil. The main chemical constituents and contents were cedrol (23.516%),phthalalic acid (11.843%),D鄄limonene (10.103%),dibutyl phthalate(9.843%) and phenol(5.324 %). ThetestofthecorrosionresistanceshowedthatHainanCypresshadstronginhibitoryongrowthonGloeophyllumtrabeumMurrand Coriolus versicolor.(4.365 % and 4.58 % of weight loss of wood sample were determined in the base and middle of Cy