端羟基超支化聚合物的合成与改性.docVIP

端羟基超支化聚合物的合成与改性 强涛涛 张国国 王学川( 教育部轻化工助剂化学与技术重点实验室 陕西科技大学 西安 710021 摘要：以催化，通过反应通过单因素实验条件：反应温度℃，反应时间h，催化剂用量为3%(以AB2单体质量计)。利用IR、等方法对的分子结构进行了表征通过的 关键词：超支化 中图分类号：O633 文献标识码：A Synthesis and Modification of Hydroxyl-terminated Hyperbranched Polymer QIANG Tao-tao, ZHANG Guo-guo, WANG Xue-chuan* (Key Laboratory of Chemistry and Technology for Light Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xian, Shaanxi, 710021) Abstract：A series hree generation of hydroxyl-terminated hyperbranched poly(amine-ester) (HPAE-OH) were synthesized by the polyesterification of 4-(bis(2-hydroxyethyl)amino)-4-oxobutanoic acid [prepared by succinic anhydride with diethanolamine (DEA)] as an AB2-type monomer with trimethylol propane (TMP) as the core moiety, proceeding in one-step procedure in the melt with p-toluenesulfonic acid (p-TSA) as catalyst, toluene as water-carrying agent. Then, it was modified by palmitoyl chloride to obtain hyperbranched polymer surfactant. The appropriate reaction conditions of hyperbranched poly(amine-ester) were optimized: the esterification reaction temperature 120℃, reaction time 8h and catalyst dosage 3% (based on total mass of monomer). The molecular structure of polymers was characterized by FTIR, 1HNMR.The surface activity of polymers was investigated by surface tension instrument, and the results indicated that it exhibited the property of typical suffactant. Key words：hyperbranched poly(amine-ester); synthesis; modification; surface activity Foundation items：National Natural Science Foundation of China ,cience and Technology Plan Program of Shaanxi Province (2011JQ2012), Doctoral Program Foundation of Shaanxi University of Science and Technology (BJ10-19), Graduate Innovation Fund of Shaanxi University of Science and Technology 超支化聚合物是一类拥有三维立体结构的高度支化的聚合物，且拥有多端基，低熔点，流变性好，溶解性能优良，反应活性高等特点[1-3]。此外，超支化聚合物在合成过程中不需要严格的保护/去保护步骤，比树枝状聚合物的合成简单而有可能实现大规模工业化生产，具有很大的应用潜力，因此人们对超支化聚合物的研究表现出了很大的兴趣[4-5]。 利用超支化聚合物多端基官能团的特点，通过