花生壳对模拟废水中Cr(Ⅵ)的动态吸附特性研究.pdfVIP

第29卷第1期 水摇 资摇 源摇 保摇 护 2013年1月 Vol.29 No.1 WATER RESOURCES PROTECTION Jan. 2013 DOI:10.3969/ j.issn.1004 6933.2013.01.020 花生壳对模拟废水中Cr(遇)的动态吸附特性研究 鲁秀国,钟摇 璐,孟摇 锋 (华东交通大学土木建筑学院,江西 南昌摇 330013) 摘要:采用废弃花生壳对质量浓度为20mg/ L的Cr(遇)模拟水样进行动态吸附实验研究。 结果表 明:在室温条件下,用粒径为1郾6 ~2郾5mm花生壳作吸附剂,用量为5郾0g,介质pH值为1郾0,流量 为3mL/ min,吸附后水样中Cr(遇)的去除率可以达到99郾08%,Cr(遇)质量浓度为0郾184mg/ L,满足 GB8978—1996《污水综合排放标准》的标准。 对模型的拟合结果表明,Thomas模型能较好地反映 吸附过程特征,花生壳饱和吸附容量为9郾4mg/ g。 从动态吸附穿透曲线中可见,219min 时达到吸 附穿透点,1312min 时达到吸附衰竭点。 关键词:吸附;花生壳;模拟废水;Cr(遇) 中图分类号:X705摇 摇 摇 文献标志码:A摇 摇 摇 文章编号:1004-6933(2013)01 0087 04 Experimental study on removing Cr(遇) from simulated wastewater by dynamic absorption with peanut shells LU Xiuguo,ZHONG Lu,MENG Feng (School of Civil Engineering andArchitecture,East China Jiaotong University,Nanchang 330013,China) Abstract:The treatment of simulated wastewater,which had a concentration of Cr(遇) of 20 mg/ L,with peanut shellswas studied through dynamic absorption experiments under different conditions. The results show that the removal rate of Cr(遇) reached99郾08% when the diameter was 1郾6 to 2郾5 mm,the adsorbent dosage of peanut -1 shellswas5郾0 g,theoptimumconditionwaspH=1郾0,andtheflowratewas3郾0 mL ·min . Theconcentrationof Cr(遇) was 0郾184 mg/ L after adsorption, meeting the Integrated Wastewater Discharge Standard (GB8978鄄 1996). The model fitting is explained in the paper. The Thomas model can well reflect the characteristics of the adsorption process,and the saturated adsorption capacity of peanut shells was9郾4 mg/ g. It can be seen from the dynamic adsorption breakthrough curvethatthepenetrativepoint andthefailurepointwerereachedat219 min