高温相变材料Li2CO3-Na2CO3 循环热稳定性分析.docVIP

第 2 卷 第 4 期  储  能 科  学  与  技  术  Vol.2 No.4 2013 年 7 月 Energy Storage Science and Technology Jul. 2013  研究开发  高温相变材料 Li2CO3-Na2CO3 循环热稳定性分析  1,2  东  1 （1 同济大学材料科学与工程学院，上海 201804；2 上海应用技术学院理学院，上海 201418）  摘  要：利用静态熔融法制备了 Li2CO3-Na2CO3（46，质量比）二元熔盐。采用自制“自动热循环测试系统”测 试了 400～600 内此二元熔盐 1010次热循环，分析了其相变参数动态变化特性，利用 DSC测试了其热稳定性， 利用 XRD分析了其化学组分。结果表明：“自动热循环测试系统”可以替代 DSC定性测试相变材料的热循环稳定 性；Li2CO3-Na2CO3二元熔盐熔化/凝固过程中主要以 LiNaCO3形式存在，其峰值温度为 499.1 ，其相变潜热为 365.5J/g；热循环过程中，此二元熔盐的熔化和凝固温度变化不大，相变潜热最大降低了 45.3J/g；通过 XRD物相分 析，可知整个循环过程中此二元熔盐的物相没有明显的变化。总之，Li2CO3-Na2CO3二元熔盐能够满足太阳能高温 热发电和其它高温储热需求。 关键词：Li2CO3-Na2CO3；热循环；稳定性 doi：10.3969/j.issn.2095-4239.2013.04.005 中图分类号：TB 332 文献标志码：A 文章编号：2095-4239（2013）04-369-08  Thermal stability of Li2CO3-Na2CO3 based high-temperature phase change materials  LI Yuefeng1,2，ZHANG Dong1 (1Department of Materials Science and Engineering，Tongji University，Shanghai 201804，China；2College of Science， Shanghai Institute of Technology，Shanghai 201418，China)  Abstract：This paper is concerned about the thermal stability of a lithium carbonate-sodium carbonate (40%Li2CO3-60%Na2CO3 by mass) based binary molten salt. A static fusion method was used to prepare the salt and the salt underwent 1010 cycles over a temperature range between 400 ℃ and 600 ℃ in an automatic thermal cycle test rig. Variation in phase change parameters and chemical compositions during the thermal cycles were analyzed by using DSC and XRD, respectively. The results show that the methodology for the thermal stability works well and primary composition of the molten salt is lithium sodium carbonate (LiNaCO3) with the peak temperature of 499.1℃ and a latent heat of 365.5 J/g. The melting(freezing) temperatures of the binary molten salt show small fluctuations during repeated thermal cycling, and the phase change latent heat is reduced by 45.3 J/g. No new compositions were detected during the thermal cycling. Key words：Li2CO3-Na2CO3；thermal stability；thermal cycli