盐度耦合FNA 对短程反硝化过程中N2O 还原的影响.docVIP

第 44 卷第 8 期 2013 年 8 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.8 Aug. 2013  盐度耦合 FNA 对短程反硝化过程中 N2O 还原的影响 刘甜甜 1, 2 ，刘牡 1 ，王淑莹 1 ，杨庆 1 ，彭永臻 1 (1. 北京工业大学北京市水质科学与水环境恢复工程重点实验室， 北京市污水脱氮除磷处理与过程控制工程技术研究中心，北京，100124； 2. 中国建筑科学研究院，北京，100013) 摘要：为研究氧化亚氮(N2O)转化过程的影响因素，采用长期处理含盐垃圾渗滤液的活性污泥进行反硝化批次试 验，考察不同 NaCl 盐度条件下，游离亚硝酸(FNA)对 N2O 还原的临界抑制质量浓度及 N2O 的积累情况。研究结 果表明：不同盐度下 FNA 对 N2O 还原的临界抑制质量浓度不同，盐度越高， FNA 对 N2O 还原的临界抑制质量 浓度越低。盐度对 N2O 的积累产生明显影响，N2O 的积累量随着盐度的增加而增高。10，20，30，35 和 40 g/L 盐度下，反硝化过程中 N2O 的最大积累量分别达到进水总氮的 19.1%，33.2%，39.0%，53.5%和 56%。污泥通过 培养驯化，可以提高其抵抗 FNA 抑制的能力，使 FNA 对 N2O 还原的临界抑制质量浓度得以提高，有利于减少 N2O 的产生。 关键词：盐度；垃圾渗滤液；反硝化；N2O 还原； 中图分类号：X703.1 文献标志码：A 文章编号：1672?7207(2013)08?3561?08  Impact of salinity coupling FNA on N2O reduction during denitrification via nitrite LIU Tiantian 1, 2 , LIU Mu 1 , WANG Shuying 1 , YANG Qing 1 , PENG Yongzhen 1 (1. Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Engineering Research Center of Beijing, Beijing University of Technology, Beijing 100124, China? 2. China Academy of Building Research, Beijing 100013, China) Abstract: In order to study the influencing factors during the conversion process of Nitrous oxide (N2O), batch tests were conducted with the sludge treating landfill leachate for a long time. In this study, the inhibitory effect of free nitrous acid (FNA) concentration on N2O reduction and accumulation at different salinity were investigated. The results show that: there are some differences of the minimum inhibition concentration of FNA on N2O reduction under different salinity, which gradually reduce as the increasing of salinity? the accumulation of N2O increases with the increase of salinity, implying that N2O production is bound up with the salinity? the accumulation of N2O at 10, 20, 30, 35 and 40 g/L salt account for 19.1%, 33.2%, 39.0%, 53.5% and 56% of infl