Zn 和Mg 质量比对7055 铝合金淬火敏感性的影响.docVIP

第 43 卷第 5 期 2012 年 5 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.43 No.5 May 2012  Zn 和 Mg 质量比对 7055 铝合金淬火敏感性的影响 张新明，陈慧，刘胜胆，刘文军，皇甫融 (中南大学材料科学与工程学院，湖南长沙，410083) 摘要：通过测定时效曲线，结合金相显微镜和透射电镜等组织观察以及 DSC 分析，研究 Zn 和 Mg 质量比(4.10 和 4.67)对 7055 铝合金淬火敏感性的影响。结果表明：在 120 时效时，合金的淬火敏感性随着时效时间的延长 而降低，而 Zn 和 Mg 质量比低的合金比 Zn 和 Mg 质量比高的合金的淬火敏感性高 7%~11%；空气淬火时，Zn 和 Mg 质量比低合金的再结晶晶粒内析出了较多粗大的 η(MgZn2)平衡相，因而减少了过饱和固溶体中溶质原子的 数量，降低合金的时效强化效果，提高合金的淬火敏感性；然而，Zn 和 Mg 质量比高的合金在空气淬火过程中析 出的 η 相较 Zn 和 Mg 质量比低的合金少，且在局部形成了 S(Al2CuMg)相。 关键词：7055 铝合金；Zn 和 Mg 质量比；淬火敏感性 中图分类号：TG146 文献标志码：A 文章编号：1672?7207(2012)05?1656?06  Effect of Zn and Mg mass ratio on quench sensitivity of aluminum alloy 7055 ZHANG Xin-ming, CHEN Hui, LIU Sheng-dan, LIU Wen-jun, HUANG Fu-rong (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: The effect of Zn and Mg mass ratio (4.1 and 4.67) on the quench sensitivity of aluminum alloy 7055 was studied by means of ageing curve testing, optical microscopy (OM), transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). The results show that the quench sensitivity decreases with the increase of ageing time at 120 ℃, and that of the alloy with lower Zn and Mg mass ratio is 7%?11% higher. There are more coarse η(MgZn2) equilibrium phases in the recrystallized grains of the alloy with lower Zn and Mg mass ratio. Consequently, fewer solute atoms are obtained from the supersaturated solid solution, and lower ageing hardening effect is achieved, which leads to the increase of quench sensitivity. In the alloy with higher Zn and Mg mass ratio, fewer η phases are precipitated during air-quenching, and S(Al2CuMg) phase is observed locally. Key words: 7055 aluminum alloy? mass ratio of Zn and Mg? quench sensitivity  7055 铝合金属于高 Zn 含量的时效强化合金，是 [1] 7055 铝合金厚板，因其具有强度高、耐腐蚀