通过能谱图研究钼酸盐复合缓蚀剂在天然海水中的缓蚀机理.docVIP

通过阻抗与能谱图研究钼酸盐复合缓蚀剂在天然海水中的缓蚀机理 柳鑫华 韩婕 孙彩云 芮玉兰 王庆辉 河北联合大学轻工学院 063000 摘要：本文采用阻抗与能谱图讨论钼酸盐复合缓蚀剂在天然海水中的缓蚀机理。首先，阻抗图谱表明：该缓蚀剂通过增大金属表面的电荷转移电阻而降低电化学腐蚀速率。Fe3O4、Fe2O3，X-射线色散能量谱(EDS)测试实验表明：添加了钼酸盐复合缓蚀剂的碳钢表面膜中钙元素含量很低（0.08%），表明缓蚀剂中具有阻垢性能的有机瞵酸盐（HEDP）和葡萄糖酸盐对海水中的Ca2+的络合分散作用而阻止了钙盐在金属表面的沉积，这也表明该缓蚀剂具有缓蚀性能同时又具有良好的阻垢性能。极低的氯元素含量（0.05%），表明缓蚀剂在碳钢表明形成的保护膜有效地抑制了海水中的氯离子对碳钢表面的腐蚀。 关键词：钼酸盐，交流阻抗谱，XPS, EDS, 海水 Mechanism of molybdate Compound Inhibitors in Sea Water with Impedance And Energy Spectrum Liu Xinhua Hanjie SunCaiyun RuiYulan WangQinghui College of Light Industry Hebei United University 063000 Abstract: The compound molybdate were tested as corrosion inhibitor and mechanism of corrosion of carbon steel in sea water was discussed by impedance and energy spectrum。First, Impedance testing show that the compound inhibitor decreases corrosion rate by increasing the charge transfer resistance of metal surface.. Second,XPS showed that the compact protective passive film was formed by inhibitor on the surface of carbon steel in seawater. The main components of the film are Fe3O4 and Fe2O3 and a little Fe3+, MoO42- and organic substance. molybdate took part in the formation of the passive film and acted as an oxide. The content of molybdate in the film is minute quantity, which indicated that molybdate only repaired the film and was not main part. Finally,X-ray dispersive spectroscopy (EDS) testing revealed that the calcium content of the film of carbon steel surface was lower when adding the compound inhibitor, only 0.08 %. It indicated that complexation and dispersion of organic phosphate (HEDP) and sodium gluconate on Ca2+ in seawater impeded the deposition of calcium on metal surface. It also showed that the compound corrosion inhibitor had good scale inhibition performance. Lower chlorine content (0.08%) indicated that the corrosion inhibitor formed a protective film on carbon steel surface, impeding chloride ion in seawater erode on the surface of carbon steel effectively. KeyWor