压敏保护膜用水性PSA 胶黏剂的研制.pdfVIP

11 1 化化 学学 与与 黏黏 合合 年第年第3333 卷第卷第22 期期 CHEMISTRYCHEMISTRY ANDAND ADHESIONADHESION ·21 · 压敏保护膜用水性PSA 胶黏剂的研制 曹 灿，林 霖，韩艳茹，赵京兰 北京东方亚科力化工科技有限公司研究中心, 北京101149） （ 摘要：研制了一种自交联型压敏保护膜用丙烯酸酯胶黏剂乳液，采用预乳化半连续聚合方法，通过氧化- 还原聚合工艺提 高树脂的相对分子质量，同时添加DAAM 和ADH 自交联单体，提高交联程度来提高压敏胶的内聚力。通过在胶黏剂乳液中加 入适量的交联剂SC- 100，进一步提高压敏胶交联程度和保护膜耐热和耐湿热等使用性能。我们可以根据SC- 100 的添加量调 配出系列保护膜压敏胶的配方，根据不同性能要求生产出不同规格的保护膜产品，利用其瞬间接着性和可再剥离性加工成压 敏保护膜可广泛用于金属、PVC、铝塑型材等的保护。 关键词：丙烯酸酯胶黏剂；压敏保护膜；氧化- 还原；自交联；交联剂；耐湿热性 中图分类号：TQ 433.436 文献标识码：A 文章编号：1001- 0017（2011）02- 0021- 04 Study on Waterborne PSA Adhesive for Pressure Sensitive Protective Film CAO Can, LIN Lin, HAN Yan-ru and ZHAO Jing-lan (Research Center of Beijing Eastern Acrylic Chemical Technology Co., Ltd, Beijing 101149, China) Abstract: A kind of acrylic binder emulsion for the self-crosslinking pressure-sensitive protective film was prepared via pre-emulsification semi-continuous polymerization. The molecular weight of resin was appropriately increased by the process of the oxidation-reduction polymerization, and the cohesive forces were improved by the increase of the cross -linking degree by the addition of DAAM and ADH as the self -crosslinking monomer. The cross-linking degree and the heat and wet-heat resistances of the protective film were further enhanced by the addition of SC-100 as the crosslinking agent, and a series of formulations were obtained by adding different amounts of SC-100. With the performance of rapid adhesion and re-peeling, the film was widely used to protect metal, PVC and aluminum-plastic material. Key words: Acrylic adhesive; pressure sensitive protective fil