有机化学双语版++Amines.pptVIP

(B) Replacement of the diazonium group by －X, －CN The preparation of aryl iodides The preparation of aryl fluorides: Treating the diazonium salt with fluoboric acid (HBF4) (69%) (81%) * Chapter 17 Amines (胺) 17.1 Amine Nomenclature 17.2 Structures of amines 17.3 Basicity of amines 17.4 Preparation of amines 17.4.1 Preparation of amines by alkylation of ammonia 17.4.2 The Gabriel synthesis of primary amines 17.4.3 Preparation of amines by reduction 17.5 Reactions of amines 17.5.1 Alkylation of amines 17.5.2 Acylation of amines 17.5.3 The Hofmann Elimination 17.5.4 Reactions of amines with nitrous acid (A) Reactions of primary aliphatic amines with nitrous acid (B) Reactions of primary arylamines with nitrous acid (C) Reactions of secondary amines with nitrous acid (D) Reactions of tertiary amines with nitrous acid 17.5.5 Synthetic transformations of aryl diazonium salt (A) Replacement of the diazonium group by －OH (B) Replacement of the diazonium group by －X, －CN (c) Replacement of the diazonium group by －H 17.5.6 Azo coupling 17.6 Spectroscopic analysis of amines 17.1 Amine Nomenclature Organic derivatives of ammonia Alkylamines Arylamines Methylamine (甲胺） Isobutylamine (异丁胺) 2-Methylpropylamine （2-甲基丙胺） Benzylamine (苄胺） Primary amines （伯胺）: P380 Aniline (苯胺) Ethylmethylamine （甲乙胺） N-Methylethylamine (N-甲基乙胺） Diethylamine （二乙胺） Secondary amines: (仲胺） Trimethylamine N,N-Dimethylmethylamine （三甲胺） （N,N-二甲基甲胺） N,N-Dimethyl- aniline (N,N-二甲基苯胺) Tertiary amines: （叔胺） Cyclohexylamine (环己胺) 1,2-Ethyldiamine （1,2-乙二胺） Diamines: Ammonium ions （铵离子） Aminium salts （铵盐） Anilinium chloride （盐酸苯胺） Quaternary ammonium salts （季铵盐） 2-Aminoethanol （2-氨基乙醇） N-Ethyl-N-methylcyclohexylamine (N-甲基-N-乙基环己胺) Heterocyclic amine: (杂环胺) Pyridine (吡啶) Pyrrole (吡咯) Quinoline (喹啉) Indole (吲哚) Py