超声波辐射对低品位氧化锌矿氨浸行为的影响.pdfVIP

第 19 卷第 5 期 中国有色金属学报 2009 年 5 月 Vol.19 No.5 The Chinese Journal of Nonferrous Metals May 2009 文章编号：1004-0609(2009)05-0960-07 超声波辐射对低品位氧化锌矿氨浸行为的影响 张玉梅，李 洁，陈启元，丁红青 ( 中南大学 化学化工学院，长沙 410083) 摘 要：研究超声波辐射对兰坪低品位氧化锌矿氨浸过程的影响规律。研究表明：无超声波辐射时，兰坪低品位 氧化锌矿在 NH -NH Cl-H O 体系中浸出 3 h 后的最高浸出率为 69.4%；引入超声波辐射后，显著缩短了浸出时间， 3 4 2 无超声波辐射时 Zn 浸出率达到 61.8%需要 80 min，而采用超声波辐射浸出时仅需20 min ；反应温度、浸出剂浓 度和 NH Cl 与 NH OH 的摩尔浓度比等参数对超声波辐射的强化作用效果显著。当反应温度和浸出剂浓度较低， 4 4 NH Cl 与 NH OH 的摩尔浓度比较大时，超声波辐射的强化作用显著；超声波辐射可望降低氨浸低品位氧化锌矿 4 4 的反应温度和浸出所需NH OH 浓度，大幅缩短浸出时间；同时，超声强化氨浸对锌的浸出具有较高选择性。 4 关键词：低品位氧化锌矿；超声波辐射；氨浸 中图分类号：TB 559 ；TF 813 ；TF 803.21 文献标识码：A Influence of ultrasonic irradiation on ammonia leaching of zinc from low-grade oxide zinc ore ZHANG Yu-mei, LI Jie, CHEN Qi-yuan, DING Hong-qing (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: The influence of ultrasonic irradiation on the ammonia leaching of zinc from low-grate oxide zinc ore from Lanping was studied. The results show that the maximum leaching rate of zinc is 69.4% in NH -NH Cl-H O solution for 3 4 2 3 h in the absence of ultrasonic. The ultrasonic can shorten the reaction time obviously. The leaching rate of 61.8% is obtained in just 20 min with ultrasonic irradiation while it needs 80 min in leaching process without ultrasonic irradiation.