微波改性锆一铝柱撑膨润土对水中Cr (VI) 的吸附.pdfVIP

化 工 环 保 1 2011年第31卷第1期 ENVIRONMENTAL PROTECT 【0N OF CHEMICAL INDUSTRY ．／ ．／ ．／ ．／ -／ ．／ ．／ ．／ G 研 究 报 告 S p ‘ ／ ‘ 微波改性锆一铝柱撑膨润土对水中Cr(VI)的吸附 唐艳葵 ，韦科陆 ，童张法 ，龙 敏 (1．广西大学 环境学院，广西 南宁530004；2．广西大学 化学化工学院，广西 南宁 530004) [摘要]以膨润土为原料，通过微波辐射加热法制备锆一铝柱撑膨润土(MZAPB)吸附剂，研究了MZAPB加入量、 溶液pH、吸附时问、温度等因素对cr(VI)吸附效果的影响。研究结果表明：当溶液初始cr(VI)质量浓度为25 mg／L、MZAPB加入量为10 L、溶液pH为5．6、吸附温度25℃、吸附时间为60 min时，cr(Ⅵ)的去除率可达到 98％以上；MZAPB对含Cr(VI)模拟废水具有较好的处理效果且在60 min内达到Cr(VI)吸附平衡；吸附等温线可 以用 Langmuir方程进行较好的拟合。 [关键词]微波辐射；锆一铝柱撑膨润土；吸附；铬(VI) [中图分类号]X703 [文献标识码]A [文章编号]1006—1878(2011)O1—0001—04 Adsorption of Cr(VI)from Water on Zirconium-Aluminum Pillared Bentonite Modified by Microwave Radiation Tang Yankui ，Wei Kelu ，Tong Zhangfa。，Long Min (1．College of Environment，Guangxi University，Nanning Guangxi 530004，China； 2．School of Chemistry and Chemical Engineering，Guangxi University，Nanning Guangxi 530004，China) Abstract：The zirconium—aluminum pillared bentonite(MZAPB)adsorbent was prepared from ben— tonite by microwave heating，and its effects on Cr(VI)adsorption were studied．The results show that：When the initial Cr(VI)mass concentration is 25 mg／L，the MZAPB dosage is 10 g／L，the SO— lution pH is 5．6，the adsorption temperature is 25 oC and the adsorption time is 60 mi n， the Cr(VI) removal rate is over 98％；The treatment effect of the simulated Cr(VI)一containing wastewater is good and the Cr(VI)adsorption equilibrium can be achieved in 60 min；The adsorption isotherm is accord． ant with Langmuir equation． Key words：microwave radiation；zirconium-aluminum pillared bentonite；adsorption；chromium(Ⅵ) 含cr废水主要来源于冶炼、电镀、印染、皮革、化