表面微纳双级阵列结构材料的开发与应用探索1Developmentand.pdfVIP

th 10 OAPS Working Paper Series Paper No. 2013-028 Website: http://www.oaps.hk/ 表面微纳双级阵列结构材料的开发与应用探索1 Development and application explorations of surface micro-nano two-level array structure materials 王红宾 吴杰飞 黄本成 杨超 施云峰 Wang Hongbin Wu Jiefei Huang Bencheng Yang Chao Shi Yunfeng 材料科学与工程学院 School of Materials Science and Engineering 摘要 表面纳米点阵材料是一种特殊的纳米材料，由于其独特的阵列结构、巨大的表面积、纳米尺度 下的高表面活性，可以表现出许多其它材料无法比拟的特殊性能，在未来各领域中有着广阔的应用 前景。本文作者在前人的研究基础上，在微米级阵列结构上复合一种纳米级结构，获得微纳双级阵 列结构材料。通过在制备过程中调整工艺参数，稳定地制备出铜针、铜线、铜枝晶三种不同微观形 貌的微纳双级阵列结构材料，并对其进行了简单的比较。这种阵列材料具有特殊的结构和高表面活 性，可以拓展诸多相关应用。作者将三种不同微观形貌的铜基微纳双级阵列结构材料作为电极催化 材料，研究了对乙醇燃料电池性能的影响，以探讨其作为电池催化材料或催化剂结构载体的可行性。 关键词：纳米阵列材料，电化学沉积，表面活性，电极催化 ABSTRACT Surface nanometer-arrayed materials have unique nanostructure with huge surface area ratio and high surface activity, which have great potential application in the future because of its various unique properties and performances. In this paper, the authors achieved surface micro-nano two-level array structure materials by fabricating nanometer structure based on micrometer structure. By changing the conditions of preparation, we successfully prepared surface micro-nano two-level array structure materials with three different microstructures, namely Cu needle array, Cu thread array, Cu dendritic array in a stable way. In this paper we also described the differenceof these microstructures. With unique structure and high surface activity, micro-nano two-level array structure materials can be used in various aspects. The authors have used such materials as electrode catalysis materials