壳聚糖碳纳米管复合膜的合成及其葡萄糖氧化酶吸附性能.pdfVIP

第5卷 第12期 2010 年 12 月 中国科技论文在线 SCIENCEPAPER ONLINE 907 壳聚糖/碳纳米管复合膜的合成及其 葡萄糖氧化酶吸附性能 1 1 1 3 1 1,2 何 侃 ，肖 南 ，于 畅 ，唐 艳 ，柳 月 ，邱介山 （1. 大连理工大学精细化工国家重点实验室炭素材料研究室，辽宁大连 116012 ； 2. 大连理工大学辽宁省微纳米技术及系统重点实验室，辽宁大连 116023 ； 3 ．辽宁师范大学化学化工学院功能材料化学研究所，辽宁大连 116029） 摘 要：碳纳米管经柠檬酸修饰、共价接枝壳聚糖及乙二醛壳聚糖交联三步处理，制备得到壳聚糖/碳纳米管复合材 料。用红外光谱(FT-IR)、紫外可见光谱(UV-Vis)、X射线衍射仪(XRD)、扫描电镜(SEM)、场发射扫描电镜(FE-SEM) 和热重分析仪(TGA)对所得复合材料进行分析表征，发现壳聚糖共价接枝交联到碳纳米管表面形成壳聚糖/碳纳米管复 合膜，复合材料中壳聚糖质量分数约占 55 %。所制备的壳聚糖/碳纳米管复合材料对葡萄糖氧化酶有很好的吸附性能。 关键词：共价接枝交联；壳聚糖/碳纳米管复合膜；吸附性能 中图分类号：TB34 文献标志码：A 文章编号：1673－7180(2010)12 －0907 －4 Preparation and adsorption performance of CA-CNTs composites 1 1 1 3 1 1,2 He Kan ，Xiao Nan ，Yu Chang ，Tang Yan ，Liu Yue ，Qiu Jieshan (1. Carbon Research Laboratory, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116012, China; 2. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116012, China; 3. Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China) Abstract: A novel biocompatible chitosan (CTS)/citric acid modified CNTs (CA-CNTs) composite has been synthesized by covalent bonding and crosslinking chemistry, in which the glyoxal were used as cross-linking reagent. The composites were characterized by FT-IR, UV-Vis, XRD, SEM, FE-SEM and TGA. The results showed that the CA-CNTs are coated by CTS to form homogeneous film-like coating. The TGA analysis of CTS/CA-CNTs reveals that the mass fraction of C