硅胶负载交联壳聚糖树脂制备及吸附性能.pdfVIP

2010 3 27 2 M ar. 2010 CHEM ICAL INDUSTRY AND ENG INEERING Vol. 27 No. 2 : 1004- 9533(2010) 02- 0132- 06 高春娟, 王俐聪, 刘骆峰, 张雨山 (, 300192) : 以壳聚糖硅胶为主要原料制备了一种硅胶负载交联壳聚糖树脂, 采用红外光谱 ( IR)X衍 射(XRD)和 描电镜( SEM )对其进行结构性能表征, 并研究了树脂对金银离子的吸附行为重 点考察了交联剂用量介质 pH 值和初始离子浓度等因素对树脂材料吸附率的影响, 试验结果表 明, 该树脂对金银离子的吸附率均大于 90% 对于金离子的吸附而言, 控制 pH值在 4, 吸附时间 90 m in时吸附率最高; 对于银离子的吸附而言,控制 pH值在 4~ 6, 吸附时间 100m in时吸附率最 高离子初始质量浓度对树脂材料的吸附率影响不大 : 壳聚糖; 硅胶;树脂; 吸附 + : TQ6304 3 : A Synthesis and Adsorption Properties of the Crosslinked Chitosan Resins Supported by SiO2 GAO Chunjuan, WANG L icong, LIU Luofeng, ZHANG Yushan ( Institute ofT ianjin Seawater D esalination andM ultipurpose U tilization, State O ceanicAdm inistration, T ianjin 300192, China) Abstract: A series of crosslinked chitosan resins supported by SiO were synthesized w ith chitosan and 2 SiO . The structuresof the crosslinked chitosan resinswere analyzed with infrared ( IR) spectroscopy, X 2 ay diffraction (XRD) and scanning electronm icroscopy ( SEM ). The adsorption capacities of the above resins forAu( ! ) andAg( ∀ ) were also studied. The effects of factors such as amountsof crosslinked a gents, media pH value and original ion concentration on the adsorption rate of the above resins were in vestigated emphatically. The results indicate that the resin has good adsorption effect onAu(! ) and Ag (∀ ). ForAu( ! ), them axmi um adsorption rate can be obtained when pH = 4, adsorption tmi e is 90 m in. ForAg( ∀ ), the max