超薄介孔碳纳米空心球的可控制备及其在超级电容器中的应用.pdfVIP

中国科技论文在线 Controlled Synthesis of Ultrathin Hollow Mesoporous Carbon Nanospheres for Supercapacitor Applications# ** DAI Yihui, JIANG Hao, HU Yanjie, FU Yao, LUO Meifang, LI Chunzhong 5 (Key Laboratory for Ultrafi ne Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China) Abstract: In this paper, ultrathin, uniform and monodisperse hollow mesoporous carbon nanospheres (HMCNs) with a thickness of ~ 3.8 nm have been synthesized by using dopamine as a carbon source. 10 The obtained HMCNs have a high specific surface area (568 m2 g−1), large pore volume (1.63 cm3 g−1), and highly accessible big mesopores (~ 9.1 nm). Notably, we realized the precise control of the shell thickness in a range of 10 nm only by tuning dopamine content. The as-obtained HMCNs, when applied as supercapacitor electrodes, demonstrate an impressive capacitive properties in 1 M H2SO4 aqueous solution, such as high specific capacitance (253 F g−1), excellent rate capability (111 F g−1 at 15 60 A g−1) and outstanding cycling stability (only 3.8% loss after 5000 cycles). The results suggest that the unique structure of the HMCNs can allow high rate of electrolyte infiltration, as well as rapid ion diffusion. The present findings push forward the development of carbon materials, exhibiting huge