Finite Space Complete Basis Method: Precision Computation of High-Resolutior Spectrum near Ionization Threshold.pdfVIP

Finite Space Complete Basis Method: Precision Computation of High-Resolutior Spectrum near Ionization Threshold.pdf

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CHIN.PHYS.LETT.Vo1.26,No.1(2009)013102 FiniteSpaceCompleteBasisM ethod:PrecisionComputationofHigh—Resolution Spectrum nearIonization Threshold GAOxiang(高翔) ,CHENShao-Hao(~ 豪) ,LIJia.Ming(李家明), DepartmentofPhysics,ShanghaiK LaboratoryforLaserFabricationandMaterialScience,ShanghaiJiaotong University,Shanghai200240 KeyLaboratory ofAtomicandMolecularNanosciencesofEducationMinistry,DepartmentofPhysics,Tsinghua University,Beijing100084 (Received20October2008) Anewmethodisproposedtodescribequantumdynamicalprocessesinfinitespacebyusingofasetofdiscretized completebases.In thismethod.thefinitespacecompletebasisisobtained bysolving theself-consistent矗eld equationwithreflectingboundaryconditions.Hence,bothnegativeandpositiveorbitalenergiescanbeobtained. Suchmethodcanbeusedinsystemswhichinvolvedynamicson』yinthereactionzone.j.e..inafinitespace.To illustratethevalidityofthemethod,wepresenttwoexamples:theoreticalcalculationofthehighexcitedstates spectra includingthecontinHum ofsodium and barium . PACS:31.15.Ar,32.70.Cs There are rich physicalprocessesin atom and usethisbasistoofrm Green’sufnctionofthesystem molecularsystems.suchasphoto-excitationand ion— andperform timeevolutionofthesystem. ization in freespaceorin externalfield,electron Inordertoillustratethevalidityofthemethodwe atom collisions,etc. These processesare very im— presentthephotoabsorptionprocessesoftheground portant in laserphysics,radiation physics,plasma stateatoms.W elusethefinitespacecompletebasis physics,atmosphericphysics,astrophysicsandsoon. methodtoperofrm precisioncomputationofthepho- Therearealreadymanysuccessfultheoretica1meth— toabsOr

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