氧化物与氟化物的加入对氯化物熔盐体系电解制备MgLa合金的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 3104−3111 Effect of oxide and fluoride addition on electrolytic preparation of Mg−La alloy in chloride molten salt Shi-dong WANG1,2 1 1 1 1 , Quan LI , Xiu-shen YE , Qing-guo SUN , Zhi-jian WU 1. Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China Received 4 September 2012; accepted 28 January 2013 Abstract: Mg−La alloys were prepared by constant voltage electrolysis in the molten salt system of MgCl −LaCl −KCl at 750 °C, 2 3 with a graphite crucible as the anode and a tungsten rod as the cathode. The effect of oxide and fluoride addition on the electrolysis was investigated comprehensively. X-ray diffraction (XRD) was used to characterize some of the Mg−La alloy products and the sludges. As the content of MgO or La2O3 in the electrolyte increased, both the current efficiency and the mass of alloy product decreased, indicating that both MgO and La O may take part in the reactions in the electrolyte. When the same mass of the oxide 2 3 was added, compared with La O , MgO had a more pronounced effect on both the current efficiency and the mass of alloy product. 2 3 XRD studies c