聚乳酸单轴拉伸膜的包装特性研究.pdfVIP

第35卷摇 第1期 摇 摇 摇 包 装 工 程 摇 摇 2014年01月 摇 摇 摇 摇 PACKAGING ENGINEERING 摇摇摇 23 技术专论 聚乳酸单轴拉伸膜的包装特性研究 于振菲,吴佳鑫,赵子龙,王爽爽,靳烨,董同力嘎 (内蒙古农业大学,呼和浩特010018) 摘要: 目的摇 研究了不同拉伸比的PLLA 薄膜的热学性能、阻隔性能和热收缩性能。 方法摇 采用双螺 杆挤流延试验机单轴拉伸制备了不同拉伸比的PLLA热收缩膜和定向拉伸膜,采用差示扫描量热分析 仪(DSC)、透湿仪和透氧仪对不同拉伸比的PLLA 薄膜的热学性能和阻隔性能进行了评估,并对PLLA 膜的热收缩性进行了测定。结果摇 热收缩膜的拉伸比由1增大到6.5 时,PLLA 的结晶度由0.2%增 加到41.8%,结晶速率明显提高,阻隔性得到了一定的改善。 随着拉伸比例的增大,热收缩率随之增 大。 定向拉伸膜的结晶度得到了大幅度提高,其阻隔性也得到了改善,但不呈现热收缩性。 结论摇 通 过单轴拉伸可以有效地提高PLLA 薄膜的结晶速率和结晶度,经过中等拉伸比例的PLLA 薄膜,其阻 湿阻氧能力相对较强。 关键词:聚乳酸;阻隔性能;结晶性能;热收缩性能 中图分类号:TB484.6摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001-3563(2014)01-0023-05 Packaging Characteristics of Uniaxially Stretched Poly(L-lactic acid) Film YUZhen-fei,WUJia-xin,ZHAOZi-long,WANGShuang-shuang,JIN Ye,DONG Tungalag (Inner Mongolia Agricultural University,Hohhot010018,China) ABSTRACT:ObjectiveTostudythethermal,barrierandthermal shrinkagepropertiesof PLLAfilmswithdifferentdrawrati鄄 os. Methods PLLA thermal shrinkagefilmswith different draw ratios and uniaxially stretched PLLA films were prepared by a twin-screw extruder. ThermalshrinkageandbarrierpropertiesofthePLLAfilmswithdifferentdrawratiosweremeasuredbyan DSC,awater vapor permeability tester and an oxygen permeability tester. Results The crystallinity of PLLA increased from 0.2% at ratio=1 to 41.8% at ratio=6.5,and the crystallization rate and crystallinity increased significantly. The barrier properties of PLLA were improved by the orientation and crystallization. The shrinkage films showed an excellent thermal shrinkage behavior,while the stretched films losted their thermal shrinkage. Conclusion Uniaxial stretching could effectively improve the crystallization rate and crystallinity of PLLA films. The moi