可加热塑料食品包装中VOCs分析.pdfVIP

摇 摇 摇 包 装 工 程 第35卷摇 第1期 摇摇摇 34 PACKAGING ENGINEERING摇 摇 摇 摇 摇 2014年01月 可加热塑料食品包装中VOCs分析 谢利,贾大鹏,慈继豪,张倩 (西安理工大学,西安710048) 摘要: 目的摇 分析可加热塑料食品包装中的挥发性有机物(VOCs)。 方法摇 以甲醇为溶剂,配制异丙 醇、乙酸乙酯、苯、乙酸丁酯、乙苯、间/ 对二甲苯、邻二甲苯、环己酮的标准溶液,利用顶空/ 气相色谱- 质谱(HS/ GC-MS)技术对7种可加热塑料食品包装进行了检测分析,对比加热前后塑料食品包装中 VOCs的变化。 结果摇 原味酸牛奶包装袋在加热后环己酮的含量明显增加,小酥肉塑料包装盒在加热 后异丙醇的含量增加比较明显,粽子塑料包装袋、玉米塑料包装袋、奶茶塑杯、自加热饭盒、微波饭盒 在加热前后VOCs含量变化不大。 结论摇 这7种包装中的苯类溶剂残留量均超标。 关键词:塑料食品包装;挥发性有机物;顶空/ 气相色谱-质谱 中图分类号:O657.7;TS206.4摇 摇 文献标识码:A摇 摇 摇 文章编号:1001-3563(2014)01-0034-04 Analysis of Volatile Organic Compounds in Heatable Plastic Food Packages XIE Li,JIA Da-peng,CI Ji-hao,ZHANG Qian (Xi忆an University of Technology,Xi忆an710048,China) ABSTRACT:ObjectiveToanalyzevolatileorganiccompoundsinheatableplasticfoodpackages. MethodsWithmethanol as solvent,standard solutions of isopropyl alcohol,ethyl acetate,benzene,butyl acetate,ethylbenzene,m/ p-Xylene,o-Xylene andcyclohexanewereprepared. Headspacegaschromatography andmassspectrometry (HS/ GC-MS)technologywereusedto determine and analyze eight volatileorganic compounds (VOCs) in sevenheatableplasticfoodpackages. Differencesof VOCs in the packages beforeandafterheatingwerecompared. ResultsThecontentof cyclohexaneinoriginalyoghurtplasticpackage after heatingwas significantly higher thanthat inunheatedpackage. The content of isopropyl alcohol inheatedXiaosurou plas鄄 tic box obviously increased. The changesinthe content of VOCsinZongziplasticbag,cornplasticbag,milkteaplastic cup, self-heating plastic dinner box and microwaveable plastic box were relatively small. Conclusion Residues