气相色谱法测定番茄、黄瓜中醚菌酯和肟菌酯残留.pdfVIP

《化学通报》在线预览版 气相色谱法测定番茄、黄瓜中醚菌酯和肟菌酯残留 1 2 1 3 1, * 章 虎 叶蓓蓓 王祥云 陈 存 吴俐勤 1 2 ( 浙江省农业科学院农产品质量标准研究所 杭州 310021 ； 浙江经贸职业学院应用工程系 杭州 310018 ； 3 长沙环境保护职业技术学院环境科学系 长沙 410004) 摘 要 建立了一种同时测定番茄、黄瓜中醚菌酯和肟菌酯农药残留的气相色谱法。以乙腈高速匀浆提取、盐析后， 再经氟罗里硅土柱层析，净化效果显著。采用气相色谱- 电子捕获检测器对待测组份进行了分离和测定。实验证明, 添加 浓度在 0.01 mg/kg、0.05 mg/kg 和 0.2 mg/kg 时，番茄、黄瓜中醚菌酯和肟菌酯添加回收率在 80.2%～103%之间，相对标 准偏差(RSD，n=5)小于 10%，醚菌酯和肟菌酯在样品中的最低检出浓度为 0.005 mg/kg 。 关键词 醚菌酯 肟菌酯 气相色谱 残留 Determination of Kresoxim-methyl and Trifloxystrobin Residues in Tomato and Cucumber by Gas Chromatography 1 2 1 3 1,* Zhang Hu , Ye Beibei , Wang Xiangyun , Chen Cun , Wu Liqin 1 ( Institute of Quality and Standard on Agricultural Products, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021; 2Department of Applied Engineering, Zhejiang Economic and Trade Polytechnic, Hangzhou 310018; 3Department of Environmental Science, Changsha Environmental Protection College, Changsha 410004) Abstract An analytical method of kresoxim-methyl and trifloxystrobin residues in tomato and cucumber by gas chromatography (GC) had been established. Samples were extracted by blending with acetonitrile and cleaned by Florisil column chromatography. The fortified recoveries of kresoxim-methyl and trifloxystrobin in tomato and cucumber samples were 80.2%～103%. Relative standard deviation was less than 10%, and the limit of detection of two pesticides in tomato and cucumber samples was 0.005 mg/kg, respectively. Keywords Kresoxim-methyl, Trifloxystrobin, Gas chrom