淋溶条件下石英砂柱中铁锰氧化物的形成特点研究分析论文.docVIP

  淋溶条件下石英砂柱中铁锰氧化物的形成 特点# 吴新亮，顾沛，王贻俊，刘凡，黄丽** 5 10 15 20 25 30 35 40 （华中农业大学资源与环境学院，武汉 430070） 摘要：用不同浓度铁锰离子混合溶液对石英砂柱进行 40 次淋溶实验，研究砂柱中铁锰氧化 物的形成状况。结果表明：（1）淋出液中铁锰离子浓度与其 pH 随着淋溶次数的增加呈现 先降低后升高的趋势，而且 pH 与铁锰浓度呈显著负相关；（2）各处理所形成的铁锰氧化 物含量之间存在极显著差异，淋溶液中铁锰浓度越大，形成的铁锰氧化物含量越高；随着淋 溶次数的增加，铁锰氧化物含量的增长逐渐减慢；不同层次铁锰氧化物含量差异显著，砂柱 下层(20-30cm)含量明显高于其他层次；（3）各阶段（每淋溶 10 次为一阶段）不同形态铁 锰氧化物含量间的相关性较高，铁锰氧化物尤其是非晶形氧化物的相对比例（Feo/Mno）随 着淋溶次数的增加逐渐增大。 关键词：石英砂柱；铁锰氧化物；淋溶；形成；地球化学 中图分类号：P595 Characteristics of iron and manganese oxides formation in the quartz sand columns under leaching condition WU Xinliang, GU Pei, WANG Yijun, LIU Fan, HUANG Li (Resources and Environment College, Huazhong Agricultural University,WuHan 430070) Abstract: The characteristics of the iron-manganese oxides formation were studied by leaching the quartz sand columns periodically with different concentrations of mixed iron and manganese ions for fourty times. The results were as follows: (1) With the leaching times increasing, the concentrations of iron and manganese ions and pH of leaching liquids generally exhibited to decline first and then to ascend, and pH was negatively correlated with the concentrations of iron and manganese ions significantly． (2) Under different treatment conditions, the extremely significant differences among the contents of iron and manganese oxides were showed. With the concentrations of iron and manganese ions in the treatments becoming higher, the contents of iron and manganese oxides coated on the sands were also raised. With the increase of leaching times, the increases of iron-manganese oxide contents slowed down. The contents of iron and manganese oxides in different layers of sand columns showed significant defferences. The contents of iron and manganese oxides in the sub layer(20-30cm) of the sand columns were significantly higher than those in the other layers．(3) The correlations between different forms of iron oxides and manganese oxides in every stage ( ten leaching times for one stage) were h