均匀设计法优化造纸黑液的湿式氧化法处理工艺.pdfVIP

中国环境科学 2013,33(7) ：1244~1251 China Environmental Science 均匀设计法优化造纸黑液的湿式氧化法处理工艺 张永利 1,2*,王承智 3,韦朝海 2, 尚玲玲 1 (1.韩山师范学院化学系生态环境研究所,广东 潮州 521041 ；2.华南理 工大学环境科学与工程学院,广东 广州 510006 ；3.环境保护部核与辐射安全中心,北京 100082) 摘要：通过均匀设计实验,对造纸黑液进行湿式氧化处理,数据回归得到 CODCr 、吸光度、浊度的回归方程,各回归方程显著,氧分压对造纸 黑液各指标影响最大;研究反应过程中反应温度、氧分压、进水 pH 值、进水浓度、搅拌强度、反应时间对造纸黑液湿式氧化(WAO)处理 的影响,6 因素优化的操作条件依次为:180℃、3.0MPa、7.25、5500mg/L、500r/min、60min;在优化的操作条件下,造纸黑液的 CODCr 、CODCr 去除率为 1661mg/L、69.8%,吸光度、脱色率为 0.63、96.3%,浊度、浊度去除率为 661NTU、74.8%.均匀设计法在造纸黑液 WAO 处理中 得到了较好的应用. 关键词：均匀设计；湿式氧化；造纸黑液；CODCr ；吸光度；浊 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2013)07-1244-08 Optimization on wet oxidation process of papermaking black liquor with uniform design method. ZHANG 1,2* 3 2 1 Yong-li , WANG Cheng-zhi , WEI Chao-hai , SHANG Ling-ling (1.Eco-environment Institute of Chemistry Department, Hanshan Normal University, Chaozhou 521041, China ；2.College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China；3. Nuclear and Radiation Safety Center Ministry of Environmental Protection, Beijing 100082, China). China Environmental Science, 2013,33(7)：1244~1251 Abstract ：Papermaking black liquor was treated in WAO process with uniform design method. The regression equations on CODCr, absorbance and turbidity were obtained by data regressions, and each regression equation was significant; Oxygen partial pressure showed the greatest impact on each indicator of papermaking black liquor. In the WAO reaction process, reaction temperature, oxygen partial pressure, influent pH value, influent concentration, stirring intensity and reaction time were researched, and the optimized six factors operating conditions were ordinally 180 ℃, 3.0MPa, 7.25