氯化钙焙烧法提取粉煤灰中的氧化铝.pdfVIP

中国环境科学 2013,33(9) ：1601~1606 China Environmental Science 氯化钙焙烧法提取粉煤灰中的氧化铝 梁振凯 1,雷雪飞 1,孙应龙 1,徐 辉 1,2,王 毅 1* (1.清华大学环境学院,北京 100084 ；2.西北核技术研究所,陕 西 西安 710024) 摘要：研究了以 CaCl2 为配料对粉煤灰进行焙烧活化,焙烧熟料水洗后,用硫酸溶液浸取以回收粉煤灰中氧化铝的方法,并考察了焙烧温度 和时间、CaCl2 加量、硫酸浓度和浸取时间等因素对氧化铝回收率的影响.采用添加 CaCl2 焙烧的方法,可高效率破坏粉煤灰中的刚玉和莫 来石,生成能被无机酸分解的物相,如钙铝黄长石、硅铝酸钙等.结果表明,按 CaCl :粉煤灰=0.8 的比例加入 CaCl ,于 900℃焙烧 30min,熟料 2 2 经水洗涤后,按照每 g 粉煤灰~30mmol 硫酸的量加入 1~4mol/L 的硫酸溶液,常温浸取 30min,氧化铝浸出率可达 95% 以上. 关键词：氯化钙；粉煤灰；焙烧；氧化铝 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2013)09-1601-06 1 1 Extraction of alumina from coal fly ash by calcination with calcium chloride process. LIANG Zhen-kai , LEI Xue-fei , SUN Ying-long1, XU Hui1,2, WANG Yi1* (1.School of Environment, Tsinghua University, Beijing 100084, China; 2.Northwest Institute of Nuclear Technology, Xi’an 710024, China). China Environmental Science, 2013,33(9)：1601~1606 Abstract ：A method of recovery of alumina from coal fly ash (CFA) is reported in this article. The method includes activation of CFA by calcination with CaCl , followed by washing with water to recover unreacted CaCl and leaching 2 2 with sulfuric acid. The technological conditions which were considered to be key factors for the success of the procedure, including calcination temperature, calcination time, CaCl2 dosage, sulfuric acid concentration and leaching time, were investigated. The experimental results indicate that calcination with CaCl2 can effectively decompose the corundum and mullite particles, which can hardly be broken down by m