上海市表层土壤中多环芳烃的分布特征与源解析.pdfVIP

中国环境科学 2014,34(4) ：989~995 China Environmental Science 上海市表层土壤中多环芳烃的分布特征与源解析 * 杜芳芳,杨 毅,刘 敏 ,陆 敏,于英鹏,郑 鑫,刘 营 (华东师范大学地理系,地理信息科学教育部重点实 验室,上海 200062) 摘要：应用气相色谱-质谱联用仪(GC-MS)对上海市 80 个表层土壤样品中 16 种优控多环芳烃的浓度进行了测定,分析了上海市土壤中 PAHs 的含量分布特征,并利用同分异构体比值、主成分分析方法对表层土壤中的 PAHs 进行了源解析.结果表明,80 个样点 PAHs 的含量在 0.12~24.5μg/g 之间,呈现出郊区市区农村的梯度变化,市区内不同功能区采样点呈现出交通区文教区公园绿地商业区住宅区的梯度 变化. PAHs 组成以 4 环和 5 环为主,平均含量分别占∑PAHs 的 49.2%和 27.0%,其次为 3 环和 6 环,分别占∑PAHs 的 14.8%和 6.6%,最低为 2 环 PAHs,仅占 2.4%,单体 PAHs 化合物以荧蒽、芘、苯并芘为主.源解析表明,表层土壤中 PAHs 的主要来源是燃烧源,主要是石油燃烧. 关键词：上海；表层土壤；多环芳烃；分布特征；源解析 中图分类号：X53 文献标识码：A 文章编号：1000-6923(2014)04-0989-07 Distribution and source apportionment of polycyclic aromatic hydrocarbons in surface soils in Shanghai. DU * Fang-fang, YANG Yi, LIU Min , LU Min, YU Ying-peng, ZHENG Xin, LIU Ying (1.Key Laboratory of Geo-Information Science of the Ministry of Education, Department of Geography, East China Normal University, Shanghai 200062, China). China Environmental Science, 2014,34(4)：989~995 Abstract ：The concentrations of sixteen priority polycyclic aromatic hydrocarbons in 80 topsoil samples in Shanghai were determined by GC-MS. The distribution pattern was discussed, and source apportionment of PAHs in surface soil was conducted by the isomer ratio and principal component analysis. Results showed that the concentrations of PAHs ranged between 0.12μg/g and 24.5μg/g, presenting gradient changes of suburburban rural and traffic areacultural and educational areapark greenbeltbusiness districtresidential in different functional areas in the city. Dominant compounds were 4rings and 5rings PAHs, which accounted for 49.2% and 27.0%, followed by 3and 6rings, which accounted for 14.8% and 6.6% of t