Mo、P含量对Ni-Mo-P化学镀层硬度及磨损率的影响规律研究论文.docVIP

河　南　科　技　学　院 2014届本科毕业论文（设计） 论文题目：Mo、P含量对Ni-Mo-P化学镀层硬度及磨损率的影响规律研究 学生姓名： 所在院系： 所学专业： 导师姓名： 完成时间：2014年月1日Ni-Mo-P化学镀配方及工艺。在参考相关工艺研究的基础上，进行两次重复共32组化学镀Ni-Mo-P试验，获得了32个镀层样品，并用扫描电子显微镜、显微硬度计和摩擦磨损试验机等手段对镀层的钼磷含量、镀层硬度和磨损性能进行了研究，遴选了一套镀层质量好的化学镀Ni-Mo-P工艺。其中镀液配比为：硫酸镍25g/L，次亚磷酸钠28g/L，柠檬酸钠20g/L,乳酸5g/L，醋酸钠15g/L，丁二酸15g/L，十二烷硫酸钠0.02g/L , 钼酸钠0~1.5g/L，用氨水调节pH值到8.5～8.8，施镀温度控制在85～90℃之间，时间t为120min时，即能得到较好的效果。 实验表明：随着添加钼酸钠的量增加，镀钼含量有增长趋势，磷含量有减低趋势，镀层硬度有先增高后降低的趋势；随着钼酸钠的添加量增长，镀层的磨损率有降低的趋势。 关键字：Ni-Mo-P，化学镀，硬度，摩擦磨损，磨损率 MO AND P CONTENT OF Ni - Mo - P CHEMICAL COATING HARDNESS AND THE WEAR RATE THE INFLUENCE LAW OF RESEARCH Abstract This paper introduces the principle and characteristics of electroless nickel plating technology and the development history and research status at home and abroad, introduced a complete set of Ni-Mo-P electroless plating formula and process.Based on the reference of related technology research, repeat twice, a total of 32 times electroless Ni-Mo-P test.Test results using an electron microscope, surface observation and other methods of phosphorus molybdenum content in the coating hardness tester to study the influence law of the wear rate, get a set of coating quality electroless Ni - Mo - P process.Ratio of the plating solution is: 25 g/L nickel sulfate, sodium phosphite 28 g/L, 20 g/L sodium citric acid, lactic acid, 5 g/L, 15 g/L sodium acetate, 15 g/L, succinic acid sodium dodecane 0.02 g/L, 0.4 g/L of sodium molybdate, pH value with ammonia to adjust to 8.5 ~ 8.8, plating temperature between 85 ~ 85 ℃, time t for 120 min., which can get better effect.Experiments show that: with the increase of the quantity of adding sodium molybdate, molybdenum content in the plating has a growth trend, had a tendency to reduce phosphorus content, coating hardness is increased after the first reduce the trend;The coating increases with the amount of adding sodium molybdate and lower wear rate trend. Key words: Ni-Mo-P