毕设说明书30万吨甲醇合成反应工段设计.docVIP

目录 With an annual output of 300000 tons of methanol synthesis process design Abstract：Currently the main raw material production of methanol was from coal and natural gas, methanol production process was distinguished into three parts, such as the production of synthesis gas (hydrogen and carbon monoxide), synthesis and refining of methanol. In the manufacture of methanol synthesis and coal and coke manufacturing process route were included methanol fuel gasification, gas desulfurization, transformation, decarburization and methanol synthesis and purification. This design for methanol synthesis and the design of the Lurgi low pressure methanol synthesis. Low-pressure methanol synthesis process was the use of low-temperature, low pressure and high activity copper-based catalyst, in 5MPa about pressure, synthesis gas from the methanol synthesis process. This design was used Lurgi methanol synthesis catalyst for the copper-based catalyst; the active component is Cu and ZnO, the catalyst of high activity. Reaction temperature was lower, at (230~270℃), low operating pressure (5-10Mpa), which widely used in methanol synthesis. The design calculations for methanol synthesis section in the production process steps, was the material balance and heat balance, and methanol and water coolers of the equipment sizing. In the design process to draw the synthesis section in the list of equipment and material flow, and was mapped the synthesis section in the PID diagrams, Synthetic tower assembly drawing and equipment layout. Keywords: methanol; Lurgi low pressur; Synthetic tower 1 绪论 1.1 甲醇的性质 甲醇是最简单的化学品之一，是重要的化工基础原料和清洁液体燃料，广泛应用于有机合成、染料、医药、农药、涂料、交通和国防等工业中。甲醇是除合成氨之外，唯一由煤经气化和天然气经重整大规模合成的化学品，是重要的一碳化工基础产品和有机化工原料。甲醇最早由木材和木质素干馏制得，故俗称木醇。 1.2 甲醇的用途 甲醇是一种重要的有机化工原料，应用广泛，可以用来生产甲醛，合成橡胶、甲胺、对苯二甲酸二甲酯、甲基苯烯酸甲酯、氯甲烷、醋酸、甲基叔丁基醚等一系列有机化工产品，而且还可以加入汽油掺或代替汽油作为动力燃料以及用来合成甲醇蛋白。随着当今世界石油资源的日益减少和甲醇单位成本的降低，用甲醇作为新的石化原料来源已经成为一种趋势。 煤制合成气 合成气净化 甲醇合成 甲醇精馏 图1 煤制甲醇的简单工艺流程 首先是采用GSP气化工